(+/-)-4-oxocyclopenten-2-enyl 2-phenylacetate

Base Information Edit

Chemical Name:(+/-)-4-oxocyclopenten-2-enyl 2-phenylacetate
CAS No.:1391630-27-5
Molecular Formula:C₁₃H₁₂O₃
Molecular Weight:216.236
Hs Code.:
Mol file:1391630-27-5.mol

Synonyms:(+/-)-4-oxocyclopenten-2-enyl 2-phenylacetate

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Chemical Property of (+/-)-4-oxocyclopenten-2-enyl 2-phenylacetate Edit

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Technology Process of (+/-)-4-oxocyclopenten-2-enyl 2-phenylacetate

There total 2 articles about (+/-)-4-oxocyclopenten-2-enyl 2-phenylacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 103-82-2
phenylacetic acid

: 59995-47-0,59995-49-2,61305-27-9,61740-29-2
4-Hydroxycyclopent-2-enone

: 1391630-27-5
(+/-)-4-oxocyclopenten-2-enyl 2-phenylacetate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 3h; Cooling with ice;
DOI:10.1016/j.tetasy.2012.05.018

Reference yield:

: 98-00-0,25212-86-6,93793-62-5
(2-furyl)methyl alcohol

: 1391630-27-5
(+/-)-4-oxocyclopenten-2-enyl 2-phenylacetate

Guidance literature:: Multi-step reaction with 2 steps

1: acetic acid / water; 1-methyl-pyrrolidin-2-one / 11 h / 240 °C / 150015 Torr / Flow reactor

2: dmap; dicyclohexyl-carbodiimide / 1-methyl-pyrrolidin-2-one; dichloromethane / 3.33 h / 20 °C / Cooling with ice

With dmap; acetic acid; dicyclohexyl-carbodiimide; In 1-methyl-pyrrolidin-2-one; dichloromethane; water;
DOI:10.1021/op400266k

Reference yield: 44.0%

: 1391630-27-5
(+/-)-4-oxocyclopenten-2-enyl 2-phenylacetate

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1391630-29-7
(R)-4-oxocyclopenten-2-enyl 2-phenylacetate

: 56745-67-6,61305-35-9,61740-33-8,61305-36-0
(4S)-4-tert-butyldimethylsilyloxycyclopent-2-en-1-one

Guidance literature:: (+/-)-4-oxocyclopenten-2-enyl 2-phenylacetate; In di-isopropyl ether; for 72h; pH=7.5; aq. phosphate buffer; Enzymatic reaction;

tert-butyldimethylsilyl chloride; With dmap; triethylamine; In tetrahydrofuran; at 20 ℃; optical yield given as %ee; enantioselective reaction; Cooling with ice;
DOI:10.1016/j.tetasy.2012.05.018