Iodomethane-d2

Base Information

• Chemical Name: Iodomethane-d2
• CAS No.: 865-43-0
• Molecular Formula: CH D2 I
• Molecular Weight: 143.923
• European Community (EC) Number: 687-210-1
• DSSTox Substance ID: DTXSID60480329
• Nikkaji Number: J570.934B
• Wikidata: Q82315035
• Mol file: 865-43-0.mol

Synonyms:Iodomethane-d2;865-43-0;dideuterio(iodo)methane;DTXSID60480329;Iodomethane-d2, >=98 atom % D, >=99% (CP), contains copper as stabilizer

Chemical Property of Iodomethane-d2

Chemical Property:

• Vapor Pressure: 437mmHg at 25°C
• Melting Point: -66.5 °C(lit.)
• Refractive Index: n20/D 1.526(lit.)
• Boiling Point: 42 °C(lit.)
• Flash Point: 7.8°C
• PSA: 0.00000
• Density: 2.313 g/mL at 25 °C
• LogP: 1.05120
• Storage Temp.: 0-6°C
• XLogP3: 1.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 143.94050
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

99% ^*data from raw suppliers

Methyl-d2Iodide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T
• Statements: 45-46-23/24/25-42/43-53-40-37/38-23/25-21
• Safety Statements: 53-23-26-36/37/39-45-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CI
• Isomeric SMILES: [2H]C([2H])I

Technology Process of Iodomethane-d2

There total 5 articles about Iodomethane-d2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

C,C-dideuterio-methanol (28563-35-1) → dideuteroiodomethane (865-43-0)

Guidance literature:

With hydrogen iodide; at 50 - 85 ℃; for 5.5h;

DOI:10.1021/jo00067a037

Reference yield:

iodomethane-d3 (865-50-9) + methyl iodide (74-88-4) → methane-d2 (676-55-1) + methane (34557-54-5,27936-85-2) + methane-d3 (676-80-2) + methane (558-20-3) + <2H1>methyl iodide (992-96-1) + dideuteroiodomethane (865-43-0)

Guidance literature:

at 434.84 ℃; under 1520.1 Torr; Time; Temperature; Kinetics; Pyrolysis;

DOI:10.1134/S1070363209120147

Reference yield:

iodoform (75-47-8) → dideuteroiodomethane (865-43-0) + diiodomethane-d2 (15729-58-5)

Guidance literature:

iodoform; With 1,4-bis(dibenzyloxy)butane; diethylzinc; In 1,2-dichloro-ethane; for 0.0833333h;

With water-d2; sulfuric acid-d2; In 1,2-dichloro-ethane; Further stages.;

DOI:10.1021/ja017230d

upstream raw materials:

C,C-dideuterio-methanol

iodoform

iodomethane-d3

methyl iodide

Downstream raw materials:

ethyl 1-{4-[methyloxy-d2]phenyl}cyclopropanecarboxylate

Refernces

• 1、 Skorobogatov,Khripun,Rebrova. "Isothermal pyrolysis of iodomethanes in gases". scheme or table. p. 2641 - 2651. Retrieved 2010/06/14.
• 2、 Charette, Andre B.,Gagnon, Alexandre,Fournier, Jean-Francois. "First evidence for the formation of a geminal dizinc carbenoid: A highly stereoselective synthesis of 1,2,3-Substituted cyclopropanes". . p. 386 - 387. Retrieved 2007/10/03.