butyloxy(diphenyl)-λ⁶-sulfanenitrile

Base Information

• Chemical Name: butyloxy(diphenyl)-λ⁶-sulfanenitrile
• CAS No.: 143885-04-5
• Molecular Formula: C₁₆H₁₉NOS
• Molecular Weight: 273.399
• Mol file: 143885-04-5.mol

Synonyms:butyloxy(diphenyl)-λ⁶-sulfanenitrile

Chemical Property of butyloxy(diphenyl)-λ⁶-sulfanenitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of butyloxy(diphenyl)-λ⁶-sulfanenitrile

There total 2 articles about butyloxy(diphenyl)-λ⁶-sulfanenitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

fluoro(diphenyl)-λ6-sulfanenitrile (67248-39-9) + sodium butanolate (2372-45-4) → butyloxy(diphenyl)-λ6-sulfanenitrile (143885-04-5)

Guidance literature:

In butan-1-ol; at 20 ℃; for 0.166667h;

DOI:10.1246/bcsj.71.1629

Reference yield:

S,S-Diphenyl-N.bromosulfilimine (42787-34-8) → butyloxy(diphenyl)-λ6-sulfanenitrile (143885-04-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 65 percent / tetrabutylammonium fluoride / tetrahydrofuran / 3 h / 0 °C

2: 51 percent / butan-1-ol / 0.17 h / 20 °C

With tetrabutyl ammonium fluoride; In tetrahydrofuran; butan-1-ol; 1: Substitution / 2: Substitution;

DOI:10.1246/bcsj.71.1629

Reference yield: 99.0%

butyloxy(diphenyl)-λ6-sulfanenitrile (143885-04-5) → butan-1-[2H]ol (4712-38-3) + S,S-diphenylsulphoximine (22731-83-5)

Guidance literature:

With [D₃]acetonitrile; water-d2; In phosphate buffer; at 20 ℃; for 0.75h; pH=6.1; Further Variations:; pH-values; Reagents; Solvents; Temperatures; Kinetics; Thermodynamic data; Product distribution;

DOI:10.1246/bcsj.73.957

upstream raw materials:

fluoro(diphenyl)-λ⁶-sulfanenitrile

sodium butanolate

S,S-Diphenyl-N_.bromosulfilimine

Downstream raw materials:

butan-1-[2H]ol

S,S-diphenylsulphoximine

acetic acid butyl ester

n-butyl phenyl ether

Refernces