1,16-Ditosyl-1,4,7,10,13,16-hexamethylpentaethylenehexamine

Base Information

• Chemical Name: 1,16-Ditosyl-1,4,7,10,13,16-hexamethylpentaethylenehexamine
• CAS No.: 141766-07-6
• Molecular Formula: C₃₀H₅₂N₆O₄S₂
• Molecular Weight: 624.913
• Mol file: 141766-07-6.mol

Synonyms:1,16-Ditosyl-1,4,7,10,13,16-hexamethylpentaethylenehexamine

Chemical Property of 1,16-Ditosyl-1,4,7,10,13,16-hexamethylpentaethylenehexamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,16-Ditosyl-1,4,7,10,13,16-hexamethylpentaethylenehexamine

There total 3 articles about 1,16-Ditosyl-1,4,7,10,13,16-hexamethylpentaethylenehexamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1,4,7,10-tetramethyl-1,4,7,10-tetraazadecane (105-78-2) + N-Methyl-N-(4-toluenesulphonyl)iodoethylamine (3409-85-6) → 1,16-Ditosyl-1,4,7,10,13,16-hexamethylpentaethylenehexamine (141766-07-6)

Guidance literature:

With potassium carbonate; In acetonitrile; Heating;

DOI:10.1016/0040-4039(92)88177-7

Reference yield:

toluene-4-sulfonic acid 2-[methyl-(toluene-4-sulfonyl)-amino]-ethyl ester (3559-06-6) → 1,16-Ditosyl-1,4,7,10,13,16-hexamethylpentaethylenehexamine (141766-07-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 100 percent / NaI / acetone / Heating

2: 100 percent / K₂CO₃ / acetonitrile / Heating

With potassium carbonate; sodium iodide; In acetone; acetonitrile;

DOI:10.1016/0040-4039(92)88177-7

Reference yield:

1,10-Ditosyl-1,4,7,10-tetramethyltriethylenetetramine (141766-05-4) → 1,16-Ditosyl-1,4,7,10,13,16-hexamethylpentaethylenehexamine (141766-07-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 96 percent / LiAlH₄ / 1,2-dimethoxy-ethane / 20 h / Heating

2: 100 percent / K₂CO₃ / acetonitrile / Heating

With lithium aluminium tetrahydride; potassium carbonate; In 1,2-dimethoxyethane; acetonitrile;

DOI:10.1016/0040-4039(92)88177-7

upstream raw materials:

1,4,7,10-tetramethyl-1,4,7,10-tetraazadecane

N-Methyl-N-(4-toluenesulphonyl)iodoethylamine

toluene-4-sulfonic acid 2-[methyl-(toluene-4-sulfonyl)-amino]-ethyl ester

1,10-Ditosyl-1,4,7,10-tetramethyltriethylenetetramine

Refernces