p-nitrosobenzaldehyde ethylene acetal

Base Information

• Chemical Name: p-nitrosobenzaldehyde ethylene acetal
• CAS No.: 242457-42-7
• Molecular Formula: C₉H₉NO₃
• Molecular Weight: 179.175
• Mol file: 242457-42-7.mol

Synonyms:p-nitrosobenzaldehyde ethylene acetal

Chemical Property of p-nitrosobenzaldehyde ethylene acetal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-nitrosobenzaldehyde ethylene acetal

There total 3 articles about p-nitrosobenzaldehyde ethylene acetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

p-hydroxylaminobenzaldehyde ethylene acetal (242457-41-6) → p-nitrosobenzaldehyde ethylene acetal (242457-42-7)

Guidance literature:

With pyridinium chlorochromate; In tetrahydrofuran; for 0.166667h;

DOI:10.1021/jo990732d

Reference yield:

2-(4-nitrophenyl)-1,3-dioxolane (2403-53-4) → p-nitrosobenzaldehyde ethylene acetal (242457-42-7)

Guidance literature:

Multi-step reaction with 2 steps

1: NH₂NH₂ / Rh/C / tetrahydrofuran; H₂O / 1 h

2: 60 percent / PCC / tetrahydrofuran / 0.17 h

With pyridinium chlorochromate; hydrazine; Rh on carbon; In tetrahydrofuran; water;

DOI:10.1021/jo990732d

Reference yield:

4-nitrobenzaldehdye (555-16-8) → p-nitrosobenzaldehyde ethylene acetal (242457-42-7)

Guidance literature:

Multi-step reaction with 3 steps

1: p-TsOH

2: NH₂NH₂ / Rh/C / tetrahydrofuran; H₂O / 1 h

3: 60 percent / PCC / tetrahydrofuran / 0.17 h

With toluene-4-sulfonic acid; pyridinium chlorochromate; hydrazine; Rh on carbon; In tetrahydrofuran; water;

DOI:10.1021/jo990732d

upstream raw materials:

p-hydroxylaminobenzaldehyde ethylene acetal

2-(4-nitrophenyl)-1,3-dioxolane

4-nitrobenzaldehdye

Downstream raw materials:

4-nitroso-benzaldehyde

N-tert-butyl-N'-[4-(2,2-dimethyl-3-methylene-cyclopropyl)-phenyl]-diazene N'-oxide

N-tert-butyl-N'-(4-diazomethyl-phenyl)-diazene N'-oxide

p-(tert-butylazoxy-NNO)benzaldehyde

Refernces