methyl 3-hydroxytridecanoate

Base Information

• Chemical Name: methyl 3-hydroxytridecanoate
• CAS No.: 150024-70-7
• Molecular Formula: C₁₄H₂₈O₃
• Molecular Weight: 244.375
• Mol file: 150024-70-7.mol

Synonyms:methyl 3-hydroxytridecanoate

Chemical Property of methyl 3-hydroxytridecanoate

Chemical Property:

• Boiling Point: 343.6±15.0 °C(Predicted)
• PKA: 13.91±0.20(Predicted)
• Density: 0.936±0.06 g/cm3(Predicted)

Purity/Quality:

99% ^*data from raw suppliers

3-hydroxy Tridecanoic Acid methyl ester ≥98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Description: 3-hydroxy Tridecanoic acid methyl ester is a hydroxylated fatty acid methyl ester and major fatty acid component of A. lipolytica and A. glycerini. It has been used in the synthesis of components of the female sex pheromone of the painted apple moth (T. anartoides). [Matreya, LLC. Catalog No. 1734]

Technology Process of methyl 3-hydroxytridecanoate

There total 6 articles about methyl 3-hydroxytridecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

methyl 3-ketotridecanoate (87900-05-8) → methyl 3-hydroxytridecanoate (150024-70-7)

Guidance literature:

With sodium tetrahydroborate; In tetrahydrofuran; at 0 ℃; for 1h;

DOI:10.1271/bbb.67.1559

Reference yield:

methanol (67-56-1) + lipopolysaccharide from Sinorhizobium fredii HH103, rkpA → 27-hydroxy-octacosanoic acid methyl ester (775341-88-3) + 3-hydroxy-octadecanoic acid methyl ester (2420-36-2) + β-hydroxyhexadecanoic acid methyl ester (51883-36-4) + methyl 3-hydroxytridecanoate (150024-70-7) + Methyl-3-hydroxypentadecanoat (112538-88-2) + β-hydroxydodecanoic acid methyl ester (72864-23-4,85464-97-7) + (+/-)-3-hydroxytetradecanoic acid methyl ester (55682-83-2) + Methyl 29-hydroxytriacontanoate + C18H36O3 (112538-92-8) + C20H40O3

Guidance literature:

With hydrogenchloride; In water; at 80 ℃; for 16h;

DOI:10.1074/jbc.ra120.013393

Reference yield:

methanol (67-56-1) + lipopolysaccharide from Sinorhizobium fredii HH103, rkpM → 27-hydroxy-octacosanoic acid methyl ester (775341-88-3) + 3-hydroxy-octadecanoic acid methyl ester (2420-36-2) + β-hydroxyhexadecanoic acid methyl ester (51883-36-4) + methyl 3-hydroxytridecanoate (150024-70-7) + Methyl-3-hydroxypentadecanoat (112538-88-2) + β-hydroxydodecanoic acid methyl ester (72864-23-4,85464-97-7) + (+/-)-3-hydroxytetradecanoic acid methyl ester (55682-83-2) + Methyl 29-hydroxytriacontanoate + C18H36O3 (112538-92-8) + C20H40O3

Guidance literature:

With hydrogenchloride; In water; at 80 ℃; for 16h;

DOI:10.1074/jbc.ra120.013393

upstream raw materials:

methyl 3-ketotridecanoate

dodecan-2-one

Decyl-oxiran

methanol

Refernces

• 1、 Hamasaki, Akiyuki,Muto, Akiko,Haraguchi, Shingo,Liu, Xiaohao,Sakakibara, Takanori,Yokoyama, Takushi,Tokunaga, Makoto. "Cobalt oxide supported gold nanoparticles as a stable and readily-prepared precursor for the in situ generation of cobalt carbonyl like species". supporting information; experimental part. p. 6869 - 6872. Retrieved 2012/02/05.
• 2、 Bishop,Hewett,Knox. "Occurrence of 3-hydroxytridecanoic and 3-hydroxypentadecanoic acids in the lipopolysaccharides of Veillonella.". . p. 274 - 276. Retrieved 2007/10/13.