Dinitrogen oxide-15N

Base Information

• Chemical Name: Dinitrogen oxide-15N
• CAS No.: 20509-24-4
• Molecular Formula: N₂O
• Molecular Weight: 45.0061
• Mol file: 20509-24-4.mol

Synonyms:(14,15)NO

Chemical Property of Dinitrogen oxide-15N

Chemical Property:

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Dinitrogen oxide-15N

There total 9 articles about Dinitrogen oxide-15N which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2Na(1+)*O(15)NNO2(2-)=Na2(15)NNO3 → nitrous oxide (35305-17-0) + (14,15)NO (20509-24-4) + dinitrogen monoxide (10024-97-2)

Guidance literature:

In water; byproducts: C6H5SO2(1-); Ar-atmosphere, pH = 9.8, 24 h; not isolated, reaction followed by mass spectrometry;

Reference yield:

sodium (15)N-nitrite (68378-96-1) + hydroxylamine hydrochloride (5470-11-1) → (15)N-nitrous oxide (20621-02-7) + nitrous oxide (35305-17-0) + (14,15)NO (20509-24-4) + dinitrogen monoxide (10024-97-2)

Guidance literature:

With phosphate buffer; In water; soln. of Na(15)NO2 in H2O and mixt. of NH2OH*HCl with phosphate buffer (pH 7-9) were degassed on the vac. line by successive freeze-pump-thaw cycles, mixed, the reaction was initiated by rotation of the vessel, after 48 h aq. phase was frozen at 194K; collected at 77K;

Reference yield:

sodium trioxodinitrate + piloty's acid (599-71-3) → nitrous oxide (35305-17-0) + (14,15)NO (20509-24-4) + dinitrogen monoxide (10024-97-2)

Guidance literature:

In water; byproducts: C6H5SO2(1-); Ar-atmosphere, pH = 9.8, 24 h; not isolated, reaction followed by mass spectrometry;

upstream raw materials:

piloty's acid

⁽¹⁵⁾N-hydroxybenzenesulfonamide

ammonia

¹⁵N labeled nitric oxide

Refernces

• 1、 Abucayon, Erwin G.,Khade, Rahul L.,Powell, Douglas R.,Zhang, Yong,Richter-Addo, George B.. "Lewis Acid Activation of the Ferrous Heme-NO Fragment toward the N-N Coupling Reaction with NO to Generate N2O". supporting information. p. 4204 - 4207. Retrieved 2018/04/05.
• 2、 Bonner, Francis T.,Ko, Younghee. "Kinetic, isotopic, and 15N NMR study of N-hydroxybenzenesulfonamide decomposition: An HNO source reaction". . p. 2514 - 2519. Retrieved 2008/10/08.