NiCO(PF₃)3

Base Information

• Chemical Name: NiCO(PF₃)3
• CAS No.: 14219-40-0
• Molecular Formula: CF₉NiOP₃
• Molecular Weight: 350.607
• Mol file: 14219-40-0.mol

Synonyms:NiCO(PF₃)3

Chemical Property of NiCO(PF₃)3

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of NiCO(PF₃)3

There total 5 articles about NiCO(PF₃)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetracarbonyl nickel (13463-39-3,71564-36-8) + trifluorophosphane (7783-55-3) → tetrakis(trifluorophosphine)nickel (13859-65-9) + NiCO(PF3)3 (14219-40-0) + Ni(trifluorophosphine)(CO)3 (14264-32-5) + Ni(CO)2(PF3)2 (13859-78-4)

Guidance literature:

In neat (no solvent); at higher temp.;;

Reference yield:

tetracarbonyl nickel (13463-39-3,71564-36-8) + trifluorophosphane (7783-55-3) → tetrakis(trifluorophosphine)nickel (13859-65-9) + NiCO(PF3)3 (14219-40-0)

Guidance literature:

In neat (no solvent); treating (Ni(CO)4) for 100 h with PF3 at 40 °C;;

DOI:10.1039/JR9510003061

Reference yield:

tetracarbonyl nickel (13463-39-3,71564-36-8) + trifluorophosphane (7783-55-3) → NiCO(PF3)3 (14219-40-0) + Ni(trifluorophosphine)(CO)3 (14264-32-5) + Ni(CO)2(PF3)2 (13859-78-4)

Guidance literature:

With Ni; In neat (no solvent); High Pressure; at 100°C;; separation by gas chromatography;;

DOI:10.1021/ic50027a011

upstream raw materials:

tetracarbonyl nickel

trifluorophosphane

Downstream raw materials:

tetrakis(trifluorophosphine)nickel

tetracarbonyl nickel

Refernces