(+)-O-menthoxycarbonyl muricatacin

Base Information

• Chemical Name: (+)-O-menthoxycarbonyl muricatacin
• CAS No.: 612084-71-6
• Molecular Formula: C₂₈H₅₀O₅
• Molecular Weight: 466.702
• Mol file: 612084-71-6.mol

Synonyms:(+)-O-menthoxycarbonyl muricatacin

Chemical Property of (+)-O-menthoxycarbonyl muricatacin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (+)-O-menthoxycarbonyl muricatacin

There total 3 articles about (+)-O-menthoxycarbonyl muricatacin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

Carbonic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester (R)-(R)-1-(tetrahydro-furan-2-yl)-tridecyl ester (612084-67-0) → (+)-O-menthoxycarbonyl muricatacin (612084-71-6) + 4-keto-5-(menthoxycarbonyloxy)heptadecanoic acid

Guidance literature:

With ruthenium trichloride; sodium periodate; sodium hydrogencarbonate; In tetrachloromethane; water; acetonitrile; at 20 ℃;

Reference yield:

tridecanal (10486-19-8) → (+)-O-menthoxycarbonyl muricatacin (612084-71-6)

Guidance literature:

Multi-step reaction with 3 steps

1: triethylborane; tert-butyl hydroperoxide / various solvent(s) / 1 h / 20 °C

2: 50 percent / pyridine / 3.17 h / 0 - 20 °C

3: 61 percent / RuCl₃*nH₂O; NaHCO₃; NaIO₄ / CCl₄; acetonitrile; H₂O / 20 °C

With pyridine; tert.-butylhydroperoxide; ruthenium trichloride; sodium periodate; triethyl borane; sodium hydrogencarbonate; In tetrachloromethane; water; acetonitrile;

Reference yield:

(S)-(S)-1-(Tetrahydro-furan-2-yl)-tridecan-1-ol → (+)-O-menthoxycarbonyl muricatacin (612084-71-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 50 percent / pyridine / 3.17 h / 0 - 20 °C

2: 61 percent / RuCl₃*nH₂O; NaHCO₃; NaIO₄ / CCl₄; acetonitrile; H₂O / 20 °C

With pyridine; ruthenium trichloride; sodium periodate; sodium hydrogencarbonate; In tetrachloromethane; water; acetonitrile;

upstream raw materials:

Carbonic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester (R)-(R)-1-(tetrahydro-furan-2-yl)-tridecyl ester

tridecanal

Refernces