Benzyl(1-benzyl-1,1-dimethylmethyl)peroxid

Base Information

• Chemical Name: Benzyl(1-benzyl-1,1-dimethylmethyl)peroxid
• CAS No.: 34577-24-7
• Molecular Formula: C₁₇H₂₀O₂
• Molecular Weight: 256.345
• Mol file: 34577-24-7.mol

Synonyms:Benzyl(1-benzyl-1,1-dimethylmethyl)peroxid

Chemical Property of Benzyl(1-benzyl-1,1-dimethylmethyl)peroxid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzyl(1-benzyl-1,1-dimethylmethyl)peroxid

There total 6 articles about Benzyl(1-benzyl-1,1-dimethylmethyl)peroxid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 9.4%

2-methyl-1-phenyl-2-propylhydroperoxide (1944-83-8) → Benzyl(1-benzyl-1,1-dimethylmethyl)peroxid (34577-24-7) + benzaldehyde (100-52-7)

Guidance literature:

With lead(IV) acetate; In Petroleum ether; for 12.5h;

DOI:10.1055/s-1981-29553

Reference yield:

2-methyl-1-phenyl-2-propylhydroperoxide (1944-83-8) → Benzyl(1-benzyl-1,1-dimethylmethyl)peroxid (34577-24-7) + benzaldehyde (100-52-7) + benzyl chloride (100-44-7) + 1,1'-(1,2-ethanediyl)bisbenzene (103-29-7) + benzyl alcohol (100-51-6,185532-71-2)

Guidance literature:

With FeCl₂(tris(2-pyridylmethyl)amine); Cyclooctan; In acetonitrile; at 25 ℃; for 2h; Product distribution; further catalysts;

Reference yield:

2-methyl-1-phenyl-2-propylhydroperoxide (1944-83-8) → Benzyl(1-benzyl-1,1-dimethylmethyl)peroxid (34577-24-7) + 1,1'-(1,2-ethanediyl)bisbenzene (103-29-7) + benzyl alcohol (100-51-6,185532-71-2)

Guidance literature:

With Cyclooctan; ⁴⁺; In acetonitrile; at 25 ℃; Product distribution; effect of mode of mixing;

DOI:10.1021/ja963627j

upstream raw materials:

2-methyl-1-phenyl-2-propylhydroperoxide

Cyclooctan

2-Methyl-1-phenyl-2-propanol

Refernces

• 1、 MacFaul, Philip A.,Ingold,Wayner,Que Jr., Lawrence. "A putative monooxygenase mimic which functions via well-disguised free radical chemistry". . p. 10594 - 10598. Retrieved 2007/10/03.
• 2、 Kropf, Heinz,Wallis, Helmut von. "1,2-Dioxane und 1,2-Dioxepane durch Barton-Typ-Reaktion aus Hydroperoxiden". . p. 633 - 635. Retrieved 2007/10/02.