2-METHYL-1-PHENYL-2-PROPYL HYDRO-PEROXIDE

Base Information

• Chemical Name: 2-METHYL-1-PHENYL-2-PROPYL HYDRO-PEROXIDE
• CAS No.: 1944-83-8
• Molecular Formula: C₁₀H₁₄O₂
• Molecular Weight: 166.22
• Mol file: 1944-83-8.mol

Synonyms:2-methyl-1-phenyl-prop-2-ylhydroperoxide;2-methyl-1-phenyl-2-propylhydroperoxide;2-methyl-1-phenylpropan-2-yl hydroperoxide;α,α-dimethylphenethyl hydroperoxide;2-METHYL-1-PHENYL-2-PROPYL HYDRO-PEROXIDE;2-methyl-1-phenylprop-2-yl hydroperoxide;MPPH;

Chemical Property of 2-METHYL-1-PHENYL-2-PROPYL HYDRO-PEROXIDE

Chemical Property:

• Refractive Index: 1.4778 (estimate)
• Boiling Point: 254.44°C (rough estimate)
• PSA: 29.46000
• Density: 1.0060 (rough estimate)
• LogP: 2.49730

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-METHYL-1-PHENYL-2-PROPYL HYDRO-PEROXIDE

There total 9 articles about 2-METHYL-1-PHENYL-2-PROPYL HYDRO-PEROXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2-methyl-1-phenyl-2-propyl bromide (23264-13-3) → 2-methyl-1-phenyl-2-propylhydroperoxide (1944-83-8)

Guidance literature:

With dihydrogen peroxide; silver trifluoroacetate; In dichloromethane; at 0 ℃;

DOI:10.1021/ja9814873

Reference yield: 79.0%

2-Methyl-1-phenyl-2-propanol (100-86-7) → 2-methyl-1-phenyl-2-propylhydroperoxide (1944-83-8)

Guidance literature:

With sulfuric acid; dihydrogen peroxide; at 0 ℃;

Reference yield: 55.0%

2,2-dimethyl-1,3-diphenyl-3-butene (830345-45-4) → 2-Methyl-1-phenyl-2-propanol (100-86-7) + 2-methyl-1-phenyl-2-propylhydroperoxide (1944-83-8) + acetophenone (98-86-2) + 3,3-dimethyl-2,4-diphenylbutan-2-yl hydroperoxide

Guidance literature:

2,2-dimethyl-1,3-diphenyl-3-butene; With triethylsilane; oxygen; [5,5-dimethyl-1-(morpholin-4-yl)hexane-1,2,4-trionato]2Co; In 1,2-dichloro-ethane; at 20 ℃; for 8h;

With hydrogenchloride; methanol; for 0.00833333h;

DOI:10.1021/jo048359j

upstream raw materials:

2-Methyl-1-phenyl-2-propanol

2-methyl-1-phenyl-2-propyl bromide

2,2-dimethyl-1,3-diphenyl-3-butene

4-phenylpivalophenone

Downstream raw materials:

1-Benzyl-1-methylethyl-p-nitroperbenzoat

Benzyl(1-benzyl-1,1-dimethylmethyl)peroxid

benzaldehyde

2-Methyl-1-phenyl-2-propanol

Refernces

• 1、 Wang, Fang,Becker, Sabine,Minier, Mikael A.,Loas, Andrei,Jackson, Megan N.,Lippard, Stephen J.. "Tuning the Diiron Core Geometry in Carboxylate-Bridged Macrocyclic Model Complexes Affects Their Redox Properties and Supports Oxidation Chemistry". supporting information. p. 11050 - 11058. Retrieved 2017/09/26.
• 2、 Shin, Jong Won,Bae, Jeong Mi,Kim, Cheal,Min, Kil Sik. "Catalysis and molecular magnetism of dinuclear iron(iii) complexes with N-(2-pyridylmethyl)-iminodiethanol/-ate". . p. 3999 - 4008. Retrieved 2014/03/21.