o-semidine

Base Information

• Chemical Name: o-semidine
• CAS No.: 17704-04-0
• Molecular Formula: C₃₂H₂₄N₂
• Molecular Weight: 436.556
• Mol file: 17704-04-0.mol

Synonyms:o-semidine

Chemical Property of o-semidine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of o-semidine

There total 6 articles about o-semidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

N-Phenyl-2-naphthylamine (135-88-6,84420-28-0) → N,N'-diphenyl-(1,1'-binaphthyl)-2,2'-diamine (17704-02-8) + 9-phenyldibenzocarbazole (21720-66-1) + o-semidine (17704-04-0)

Guidance literature:

With acetic acid; silver(l) oxide; In toluene; at 60 ℃; for 2h; Sealed tube;

DOI:10.1039/c9cc05240b

Reference yield: 40.0%

N-phenyl 2-naphthyl nitroxide (27067-31-8) → 2-(phenylamino)naphthoquinone (6628-97-3) + N-Phenyl-2-naphthylamine (135-88-6,84420-28-0) + 4-(N-phenyl-2-naphthylamino)-1,2-naphthoquinone (21720-69-4) + o-semidine (17704-04-0)

Guidance literature:

In benzene; for 336h; Further byproducts given; Ambient temperature; in the dark;

Reference yield:

N-phenyl 2-naphthyl nitroxide (27067-31-8) → N-Phenyl-2-naphthylamine (135-88-6,84420-28-0) + N,N'-diphenyl-(1,1'-binaphthyl)-2,2'-diamine (17704-02-8) + 4-(N-phenyl-2-naphthylamino)-1,2-naphthoquinone (21720-69-4) + o-semidine (17704-04-0)

Guidance literature:

With tert.-butylhydroperoxide; cobalt(II) 4-methylbenzoate; In benzene; for 16h; Further byproducts given; Ambient temperature;

upstream raw materials:

N-Phenyl-2-naphthylamine

N-phenyl 2-naphthyl nitroxide

Refernces

• 1、 Forrester, Alexander R.,Fullerton, Joseph D.,McConnachie, Gordon. "Nitroxide Radicals. Part 21. Spontaneous Decomposition of N-Aryl 1- and 2-Naphthyl Nitroxides". . p. 1759 - 1764. Retrieved 2007/10/02.