1-Propanol, 2,2,3,3,3-pentafluoro-, Methanesulfonate

Base Information

• Chemical Name: 1-Propanol, 2,2,3,3,3-pentafluoro-, Methanesulfonate
• CAS No.: 813-31-0
• Molecular Formula: C₄H₅F₅O₃S
• Molecular Weight: 228.14
• Mol file: 813-31-0.mol

Synonyms:<1H,1H-Pentafluor-propyl>-methansulfonat

Chemical Property of 1-Propanol, 2,2,3,3,3-pentafluoro-, Methanesulfonate

Chemical Property:

• Boiling Point: 112-114 °C(Press: 70 Torr)
• Density: 1.528±0.06 g/cm3(Predicted)

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-Propanol, 2,2,3,3,3-pentafluoro-, Methanesulfonate

There total 1 articles about 1-Propanol, 2,2,3,3,3-pentafluoro-, Methanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2,2,3,3,3-pentafluoropropyl alcohol (422-05-9) + methanesulfonyl chloride (124-63-0) → <1H,1H-Pentafluor-propyl>-methansulfonat (813-31-0)

Guidance literature:

With triethylamine; In chloroform; for 6h; Ambient temperature;

DOI:10.1016/S0022-1139(96)03490-2

Reference yield: 23.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + <1H,1H-Pentafluor-propyl>-methansulfonat (813-31-0) → 4-nitro-1-(2,2,3,3,3-pentafluoropropoxy)benzene (109230-70-8)

Guidance literature:

With sodium hydride; In N,N,N,N,N,N-hexamethylphosphoric triamide; 1.) r.t., 2.) 110 deg C, 8 h;

DOI:10.1016/S0022-1139(96)03490-2

Reference yield:

<1H,1H-Pentafluor-propyl>-methansulfonat (813-31-0) → 2,2,3,3,3-pentafluoropropyl amine (422-03-7)

Guidance literature:

With ammonium hydroxide; at 175 ℃; for 24h;

DOI:10.1021/jo01068a091

upstream raw materials:

2,2,3,3,3-pentafluoropropyl alcohol

methanesulfonyl chloride

Downstream raw materials:

2,2,3,3,3-pentafluoropropyl amine

4-nitro-1-(2,2,3,3,3-pentafluoropropoxy)benzene

Refernces