LANTHANUM OXALATE

Base Information

• Chemical Name: LANTHANUM OXALATE
• CAS No.: 6451-21-4
• Molecular Formula: 3C₂O₄*10H₂O*2La
• Molecular Weight: 722.023
• Mol file: 6451-21-4.mol

Synonyms:Ethanedioicacid, lanthanum(3+) salt (3:2), nonahydrate (9CI); Oxalic acid, lanthanum(3+)salt (3:2), nonahydrate (8CI); Lanthanum oxalate nonahydrate; Lanthanumsesquioxalate nonahydrate

Chemical Property of LANTHANUM OXALATE

Chemical Property:

• PSA: 240.78000
• LogP: -10.54140

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of LANTHANUM OXALATE

There total 15 articles about LANTHANUM OXALATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

Dimethyl oxalate (553-90-2) + lanthanide(III)chloride heptahydrate → lanthanum(III) oxalate decahydrate (6451-21-4,7100-77-8,10171-46-7,13077-33-3,14895-97-7,14977-50-5,18901-18-3,29985-97-5,70063-08-0,70063-09-1)

Guidance literature:

In water; benzene; at 15 ℃; for 24h;

DOI:10.1039/c6dt02677j

Reference yield:

Dimethyl oxalate (553-90-2) → lanthanum(III) oxalate decahydrate (6451-21-4,7100-77-8,10171-46-7,13077-33-3,14895-97-7,14977-50-5,18901-18-3,29985-97-5,70063-08-0,70063-09-1)

Guidance literature:

With nitric acid; In water; stirring, heating on water bath for 3 h, standing overnight at room temp.; filtrn., washed with ethanol, ether, dried for 24 h in air at room temp.;

DOI:10.1021/ac60133a015

Reference yield:

ammonium oxalate + lanthanum acetate tetrahydrate → lanthanum(III) oxalate decahydrate (6451-21-4,7100-77-8,10171-46-7,13077-33-3,14895-97-7,14977-50-5,18901-18-3,29985-97-5,70063-08-0,70063-09-1)

Guidance literature:

With NH₄OH; In acetic acid; dropwise addn. of hot 4% ammonium oxalate soln. to a stirred soln. of La(CH3COO)3*4H2O in glacial acetic acid, neutralization to pH = 7 with NH4OH; pptn., holding at room temp. for 1 h, filtration, washing with dilutes (NH4)2C2O4, drying at 80°C;

DOI:10.1016/S0040-6031(01)00834-6

upstream raw materials:

oxalic acid

lanthanum(III) oxalate decahydrate

water

lanthanum(III) chloride

Downstream raw materials:

oxalic acid ; dilanthanum (III)-compound

Refernces

• 1、 Zottnick, Sven H.,Sorg, Jens R.,Sprenger, Jan A. P.,Finze, Maik,Müller-Buschbaum, Klaus. "Unexpected Dimeric Spiro-Borate Complexes from Lewis-Acid Induced Transformation of Oxalatoborates". supporting information. p. 53 - 59. Retrieved 2017/02/05.
• 2、 Okawa, Hisashi,Sadakiyo, Masaaki,Otsubo, Kazuya,Yoneda, Ko,Yamada, Teppei,Ohba, Masaaki,Kitagawa, Hiroshi. "Proton Conduction Study on Water Confined in Channel or Layer Networks of LaIIIMIII(ox)3·10H2O (M = Cr, Co, Ru, La)". . p. 8529 - 8535. Retrieved 2015/09/21.