3-Butenyltrimethylsilane

Base Information

• Chemical Name: 3-Butenyltrimethylsilane
• CAS No.: 763-13-3
• Molecular Formula: C7H16Si
• Molecular Weight: 128.29
• Hs Code.: 2931900090
• European Community (EC) Number: 878-414-3
• NSC Number: 96809
• DSSTox Substance ID: DTXSID00294482
• Nikkaji Number: J377.115F
• Wikidata: Q72513901
• Mol file: 763-13-3.mol

Synonyms:3-BUTENYLTRIMETHYLSILANE;763-13-3;but-3-enyl(trimethyl)silane;4-(Trimethylsilyl)but-1-ene;Silane,3-buten-1-yltrimethyl-;but-3-enyltrimethylsilane;3-Buten-1-Yl(Trimethyl)Silane;NSC96809;4-But-1-enyltrimethylsilane;3-Butenyl(trimethyl)silane #;(but-3-en-1-yl)trimethylsilane;DTXSID00294482;AMY24685;MFCD00054880;NSC-96809;AKOS006342979;AS-59671;B6225;FT-0653302;D93230;A838671

Chemical Property of 3-Butenyltrimethylsilane

Chemical Property:

• Vapor Pressure: 25.9mmHg at 25°C
• Melting Point: < 0 °C
• Refractive Index: 1.4102
• Boiling Point: 112.2 °C at 760 mmHg
• Flash Point: 11.8 °C
• PSA: 0.00000
• Density: 0.733 g/cm³
• LogP: 2.90070
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 128.102127045
• Heavy Atom Count: 8
• Complexity: 68.9

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-(Trimethylsilyl)but-1-ene 97% ^*data from reagent suppliers

Safty Information:

• Statements: 11
• Safety Statements: 9-16-33

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)CCC=C

Technology Process of 3-Butenyltrimethylsilane

There total 4 articles about 3-Butenyltrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

(E)-1,4-bis(trimethylsilyl)but-2-ene (16054-35-6) → Hexamethyldisiloxane (107-46-0) + but-3-en-1-yltrimethylsilane (763-13-3)

Guidance literature:

With sulfuric acid; In pentane; at 0 ℃; for 0.5h; further reagent trifluoroacetic acid;

DOI:10.1021/jo970546c

Reference yield:

(but-3-enyl)(chloromethyl)dimethylsilane (33558-80-4) → 1,1-dimethyl-1-silacyclohexane (4040-74-8) + 1,1,3-trimethyl-1-silacyclopentane (17936-93-5) + but-3-en-1-yltrimethylsilane (763-13-3) + C7H15Si

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In various solvent(s); at 25 ℃; Irradiation;

DOI:10.1021/ja00407a058

Reference yield:

(but-3-enyl)(chloromethyl)dimethylsilane (33558-80-4) → 1,1-dimethyl-1-silacyclohexane (4040-74-8) + 1,1,3-trimethyl-1-silacyclopentane (17936-93-5) + but-3-en-1-yltrimethylsilane (763-13-3)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In various solvent(s); at 25 ℃; for 3h; Irradiation;

DOI:10.1021/ja00407a058

upstream raw materials:

(but-3-enyl)(chloromethyl)dimethylsilane

(E)-1,4-bis(trimethylsilyl)but-2-ene

Downstream raw materials:

chloro-trimethyl-silane

trans-1-(phenylsulfonyl)-4-(trimethylsilyl)-1-butene

1-butylene

methane

Refernces

• 1、 Wilt, James W.. "REACTIVITY AND SELECTIVITY IN THE CYCLIZATION OF SILA-5-HEXEN-1-YL CARBON-CENTERED RADICALS". . p. 3979 - 4000. Retrieved 2007/10/02.