Phenyl thiomethacrylate

Base Information

• Chemical Name: Phenyl thiomethacrylate
• CAS No.: 54667-28-6
• Molecular Formula: C10H10OS
• Molecular Weight: 178.255
• Hs Code.: 2930909090
• Mol file: 54667-28-6.mol

Synonyms:Phenyl thiomethacrylate;S-Phenyl thiomethacrylate

Chemical Property of Phenyl thiomethacrylate

Chemical Property:

• PSA: 58.39000
• LogP: 2.14790

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phenyl thiomethacrylate

There total 3 articles about Phenyl thiomethacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

thiophenol (108-98-5) + Methacryloyl chloride (920-46-7,26937-45-1) → S-phenyl 2-methylpropenethioate (54667-28-6)

Guidance literature:

With potassium hydroxide; tetrabutylammomium bromide; 4-methoxy-phenol; In dichloromethane; water; at 0 ℃; for 1h;

Reference yield:

2,6-di-tert-butyl-4-methyl-phenol (128-37-0) + thiophenol (108-98-5) → S-phenyl 2-methylpropenethioate (54667-28-6)

Guidance literature:

With sodium hydroxide; In water;

Reference yield:

4-nitrophenyl methacrylate (16522-41-1) + thiophenol (108-98-5) → S-phenyl 2-methylpropenethioate (54667-28-6) + p-nitrophenyl 3-phenylthio-2-methylpropionate

Guidance literature:

With TEA; In 1-methyl-pyrrolidin-2-one; at 20 ℃; for 2h;

DOI:10.1021/ma025712j

upstream raw materials:

thiophenol

Methacryloyl chloride

4-nitrophenyl methacrylate

2,6-di-tert-butyl-4-methyl-phenol

Downstream raw materials:

S-methacryloyl-coenzyme-A

Refernces

• 1、 Tsuchiya, Kousuke,Shibasaki, Yuji,Ueda, Mitsuru. "Tandem type polymerization. Synthesis and characterization of ordered poly(amide-thioether) from 2,6-dichlorophenyl methacrylate, 4,4′-thiobis(benznenethiol), and 4,4′-oxydianiline". . p. 1815 - 1818. Retrieved 2007/10/03.