1-formyloxy-2-trimethylsiloxyethane

Base Information

• Chemical Name: 1-formyloxy-2-trimethylsiloxyethane
• CAS No.: 128728-88-1
• Molecular Formula: C₆H₁₄O₃Si
• Molecular Weight: 162.261
• Mol file: 128728-88-1.mol

Synonyms:1-formyloxy-2-trimethylsiloxyethane

Chemical Property of 1-formyloxy-2-trimethylsiloxyethane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-formyloxy-2-trimethylsiloxyethane

There total 5 articles about 1-formyloxy-2-trimethylsiloxyethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.6%

2-ethoxy-1,3-dioxolane (4544-20-1) + Hexamethyldisiloxane (107-46-0) → 1,2-di(1,3-dioxolan-2-yloxy)ethane (4544-19-8) + ethyl trimethylsilyl ether (1825-62-3) + 2,2,7,7-tetramethyl-3,6-dioxa-2,7-disilaoctane (7381-30-8) + 1-formyloxy-2-trimethylsiloxyethane (128728-88-1)

Guidance literature:

sulfuric acid; at 20 ℃; for 1h; Yield given;

DOI:10.1007/BF00473860

Reference yield:

2-ethoxy-1,3-dioxolane (4544-20-1) + tert-butoxytrimethylsilane (13058-24-7) → ethyl trimethylsilyl ether (1825-62-3) + 1-formyloxy-2-trimethylsiloxyethane (128728-88-1) + 1-tert-butoxy-2-trimethylsiloxy ethane (129345-72-8) + 1-formyloxy-2-tert-butoxy ethane (129345-71-7)

Guidance literature:

at 16 - 20 ℃; for 1h; Further byproducts given;

Reference yield:

2-ethoxy-1,3-dioxolane (4544-20-1) + Hexamethyldisiloxane (107-46-0) → ethyl trimethylsilyl ether (1825-62-3) + 2,2,7,7-tetramethyl-3,6-dioxa-2,7-disilaoctane (7381-30-8) + 1-formyloxy-2-trimethylsiloxyethane (128728-88-1) + formic acid ethyl ester (109-94-4)

Guidance literature:

nitric acid; at 20 ℃; for 24h; Product distribution; var. catalysts, reaction times, educt ratios, temperatures, other dioxolane;

upstream raw materials:

2-ethoxy-1,3-dioxolane

tert-butoxytrimethylsilane

Hexamethyldisiloxane

2,2,7,7-tetramethyl-3,6-dioxa-2,7-disilaoctane

Refernces

• 1、 Zhurkina, I. P.,Nedogrei, E. P.,Musavirov, R. S.,Kondrat'eva, I. A.,Rakhmankulov, D. L.. "REACTION OF tert-BUTOXYTRIMETHYLSILANE WITH 2-ETHOXY-1,3-DIOXOLANE". . p. 349 - 353. Retrieved 2007/10/02.