S-nitrosocyclohexanethiol

Base Information

• Chemical Name: S-nitrosocyclohexanethiol
• CAS No.: 15459-94-6
• Molecular Formula: C₆H₁₁NOS
• Molecular Weight: 145.225
• Mol file: 15459-94-6.mol

Synonyms:S-nitrosocyclohexanethiol

Chemical Property of S-nitrosocyclohexanethiol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of S-nitrosocyclohexanethiol

There total 1 articles about S-nitrosocyclohexanethiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Cyclohexanethiol (1569-69-3) → S-nitrosocyclohexanethiol (15459-94-6)

Guidance literature:

With magnesium hydrogen sulfate; silica gel; sodium nitrite; In dichloromethane; at 20 ℃;

DOI:10.1080/00397910008087194

Reference yield: 85.0%

tribenzyl phosphite (15205-57-9) + S-nitrosocyclohexanethiol (15459-94-6) → thiophosphoric O,O'-dibenzyl ester S-cyclohexyl ester

Guidance literature:

In aq. phosphate buffer; acetonitrile; at 20 ℃; for 1h; pH=7.4; Time;

DOI:10.1021/acs.orglett.8b03393

Reference yield: 80.0%

S-nitrosocyclohexanethiol (15459-94-6) → 1,2-dicyclohexyl disulfide (2550-40-5)

Guidance literature:

With air; In chloroform; at 20 ℃; for 0.416667h;

DOI:10.1016/S0040-4020(02)00390-3

upstream raw materials:

Cyclohexanethiol

Downstream raw materials:

1,2-dicyclohexyl disulfide

S-cyclohexyl cyclohexane-1-sulfonothioate

Refernces

• 1、 Iranpoor,Firouzabadi,Heydari. "Efficient conversion of thiols to S-nitrosothiols with the 18-crown-6 complex of N2O4 as a new nitrosating agent". . p. 668 - 669. Retrieved 1999.
• 2、 Iranpoor, Nasser,Firouzabadi, Habib,Pourali, Ali Reza. "Dinitrogen tetroxide-impregnated charcoal (N2O 4/charcoal): Selective nitrosation of amines, amides, ureas, and thiols". . p. 1517 - 1526. Retrieved 2007/10/03.