(2-nitrobenzyl)(phenyl)sulfane

Base Information

• Chemical Name: (2-nitrobenzyl)(phenyl)sulfane
• CAS No.: 91718-67-1
• Molecular Formula: C₁₃H₁₁NO₂S
• Molecular Weight: 245.302
• Mol file: 91718-67-1.mol

Synonyms:(2-nitrobenzyl)(phenyl)sulfane

Chemical Property of (2-nitrobenzyl)(phenyl)sulfane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (2-nitrobenzyl)(phenyl)sulfane

There total 7 articles about (2-nitrobenzyl)(phenyl)sulfane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

potassium 2-(2-nitrophenyl)acetate (1316859-98-9) + diphenyldisulfane (882-33-7) → (2-nitrobenzyl)(phenyl)sulfane (91718-67-1)

Guidance literature:

In dimethyl sulfoxide; at 80 ℃; for 24h; Inert atmosphere;

DOI:10.1039/d1ra00063b

Reference yield: 39.0%

thiophenol (108-98-5) + 2-nitrophenylmethyl bromide (3958-60-9) → (2-nitrobenzyl)(phenyl)sulfane (91718-67-1)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 4h;

DOI:10.1021/acs.orglett.5b01552

Reference yield: 27.0%

bis(phenylthio)methane (3561-67-9) + nitrobenzene (98-95-3,26969-40-4) → 4-nitrobenzylphenyl sulfide (7703-38-0) + (2-nitrobenzyl)(phenyl)sulfane (91718-67-1) + ((2-nitrophenyl)methylene)bis(phenylsulfane) (93304-97-3)

Guidance literature:

With potassium tert-butylate; In dimethyl sulfoxide; for 0.5h; Product distribution; Ambient temperature;

DOI:10.1021/jo00200a059

upstream raw materials:

bis(phenylthio)methane

nitrobenzene

sodium thiophenolate

2-nitrophenylmethyl bromide

Downstream raw materials:

2-(phenylsulfonylmethyl)-1-nitrobenzene

2-<(phenylthio)methyl>aniline

1-(Benzenesulfonyl-methylsulfanyl-methyl)-2-nitro-benzene

Refernces

• 1、 Villuendas, Pedro,Urriolabeitia, Esteban P.. "Ru-Catalyzed Regioselective CH-Hydroarylation of Alkynes with Benzylthioethers Using Sulfur as Directing Group". supporting information. p. 3178 - 3181. Retrieved 2015/06/30.
• 2、 Esakkidurai,Vijaikumar,Madhavan,Pitchumani. "Preparation of unsymmetrical sulfides using modified zeolite catalysts". . p. 3142 - 3144. Retrieved 2007/10/03.