Tetrachloro(trichloromethyl)phosphorane

Base Information

• Chemical Name: Tetrachloro(trichloromethyl)phosphorane
• CAS No.: 3582-10-3
• Molecular Formula: CCl7 P
• Molecular Weight: 291.156
• European Community (EC) Number: 222-705-4
• UNII: BUG6XZT3UD
• DSSTox Substance ID: DTXSID50189354
• Nikkaji Number: J216.216D
• Wikidata: Q83061411
• Mol file: 3582-10-3.mol

Synonyms:Tetrachloro(trichloromethyl)phosphorane;3582-10-3;BUG6XZT3UD;UNII-BUG6XZT3UD;EINECS 222-705-4;Phosphorane,tetrachloro(trichloromethyl)-, (TB-5-12)- (9CI);DTXSID50189354;trichloromethyltetrachlorophosphorus;tetrachloro-(trichloromethyl)-phosphorane;tetrachloro(trichloromethyl)-lambda5-phosphane;(TB-5-12)-Tetrachloro(trichloromethyl)phosphorane;Phosphorane, tetrachloro(trichloromethyl)-, (TB-5-12)-

Chemical Property of Tetrachloro(trichloromethyl)phosphorane

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 13.59000
• Density: g/cm³
• LogP: 5.48260
• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 289.752781
• Heavy Atom Count: 9
• Complexity: 104

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(P(Cl)(Cl)(Cl)Cl)(Cl)(Cl)Cl

Technology Process of Tetrachloro(trichloromethyl)phosphorane

There total 4 articles about Tetrachloro(trichloromethyl)phosphorane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyldichlorophosphane (676-83-5) → tetrachloro(trichloromethyl)phosphorane (3582-10-3)

Guidance literature:

With chlorine; In dichloromethane; at 59.9 - 69.9 ℃;

Reference yield:

Tetrachloromethylphosphane (2725-68-0) → tetrachloro(trichloromethyl)phosphorane (3582-10-3)

Guidance literature:

With dichloromethane; at 69.9 - 79.9 ℃; also with CCl₄ as reagent;

DOI:10.1039/DT9900002593

Reference yield:

dichloro(chloromethyl)phosphine (2155-78-4) → tetrachloro(trichloromethyl)phosphorane (3582-10-3)

Guidance literature:

With tetrachloromethane; chlorine;

upstream raw materials:

dichloro(chloromethyl)phosphine

methyldichlorophosphane

Tetrachloromethylphosphane

Downstream raw materials:

trichloromethylphosphonous dichloride

trichloromethylphosphonyl dichloride

C₇H₄Cl₆NP

C₇H₄Cl₅N₂O₂P

Refernces

• 1、 Ali, Rusmidah,Dillon, Keith B.. "Some Novel Phosphoranides containing Pentafluorophenyl Groups". . p. 2593 - 2596. Retrieved 2007/10/02.