LITHIUM FORMATE

Base Information

• Chemical Name: LITHIUM FORMATE
• CAS No.: 556-63-8
• Molecular Formula: CHLiO2
• Molecular Weight: 51.9587
• Mol file: 556-63-8.mol

Synonyms:LITHIUM FORMATE;FORMIC ACID LITHIUM SALT;Lithiumformiat;Lithiummethanoat;lithiummethanoate;Lithiumformiate-1-hydrate;Lithiumformiatemonohydrate

Chemical Property of LITHIUM FORMATE

Chemical Property:

• Melting Point: 8.4oC
• Refractive Index: ">
• Boiling Point: 100.6°Cat760mmHg
• Flash Point: 29.9°C
• PSA: 40.13000
• Density: g/cm³
• LogP: -0.99800

Purity/Quality:

99% ^*data from raw suppliers

Lithium formate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38-67-36
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of LITHIUM FORMATE

There total 25 articles about LITHIUM FORMATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(CH3)2(C3HN2Ge)(2,6-iPr2C6H3)2OCHO (1109286-34-1) → (HC(CMeNC-2,6-i-Pr2C6H3)2)-germanium(II) hydride (382150-90-5) + lithium formate (556-63-8)

Guidance literature:

With n-butyllithium; borane-ammonia complex; In tetrahydrofuran; hexane; at -78 - 20 ℃;

DOI:10.1039/c0dt00921k

Reference yield: 56.6%

lithium bicarbonate (5006-97-3) → lithium formate (556-63-8)

Guidance literature:

With hydrogen; In water; at 100 ℃; for 10h; under 30003 Torr; Autoclave;

DOI:10.1002/anie.201409500

Reference yield:

lithium tert-butyl hydroperoxide (14680-31-0) + acetophenone (98-86-2) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + lithium formate (556-63-8) + lithium benzoate (553-54-8) + tert-butyl alcohol (75-65-0)

Guidance literature:

lithium tert-butoxide; In n-heptane; at 40 ℃; Rate constant; Kinetics; other solvents and inhibitors investigated; Energy of activation, A-factor;;

upstream raw materials:

calcium diformate

lithium tert-butyl hydroperoxide

acetophenone

acetone

Downstream raw materials:

3-phenyl-propenal

formic acid

carbon monoxide

4-methyl-2-nitrobenzoic acid

Refernces

• 1、 Mouaine,Becker,Carabatos-Nedelec. "Thermal and spectroscopic study of dehydration of lithium formate monohydrate single-crystals". . p. 807 - 816. Retrieved 1999.
• 2、 Huang, Zhimei,Zeng, Haipeng,Xie, Meilan,Lin, Xing,Huang, Zhaoming,Shen, Yue,Huang, Yunhui. "A Stable Lithium–Oxygen Battery Electrolyte Based on Fully Methylated Cyclic Ether". supporting information. p. 2345 - 2349. Retrieved 2019/02/01.
• 3、 Liu, Tao,Frith, James T.,Kim, Gunwoo,Kerber, Rachel N.,Dubouis, Nicolas,Shao, Yuanlong,Liu, Zigeng,Magusin, Pieter C. M. M.,Casford, Michael T. L.,Garcia-Araez, Nuria,Grey, Clare P.. "The Effect of Water on Quinone Redox Mediators in Nonaqueous Li-O2 Batteries". . p. 1428 - 1437. Retrieved 2018/02/09.