1-nitroxybicyclo<3.3.1>nonane

Base Information

• Chemical Name: 1-nitroxybicyclo<3.3.1>nonane
• CAS No.: 157774-18-0
• Molecular Formula: C₉H₁₅NO₃
• Molecular Weight: 185.223
• Mol file: 157774-18-0.mol

Synonyms:

Chemical Property of 1-nitroxybicyclo<3.3.1>nonane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-nitroxybicyclo<3.3.1>nonane

There total 2 articles about 1-nitroxybicyclo<3.3.1>nonane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bicyclo[3.3.1]nonane (280-65-9) → 1-Hydroxybicyclo<3.3.1>nonane (15158-56-2) + 1-nitrobicyclo[3.3.1]nonane + 1-nitrosobicyclo[3.3.1]nonane + 1-nitroxybicyclo<3.3.1>nonane (157774-18-0)

Guidance literature:

With dinitrogen pentoxide; In tetrachloromethane; at 15 - 20 ℃; for 1h;

DOI:10.1134/S107042802010005X

Reference yield:

bicyclo[3.3.1]nonane-3,7-dione (770-15-0) → 1-Hydroxybicyclo<3.3.1>nonane (15158-56-2) + 1-nitrobicyclo[3.3.1]nonane + 1-nitrosobicyclo[3.3.1]nonane + 1-nitroxybicyclo<3.3.1>nonane (157774-18-0)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrazine hydrate; potassium hydroxide / diethylene glycol / 3 h / Reflux

2: dinitrogen pentoxide / tetrachloromethane / 1 h / 15 - 20 °C

With dinitrogen pentoxide; hydrazine hydrate; potassium hydroxide; In tetrachloromethane; diethylene glycol;

DOI:10.1134/S107042802010005X

Reference yield:

1-nitroxybicyclo<3.3.1>nonane (157774-18-0) → 1-Hydroxybicyclo<3.3.1>nonane (15158-56-2)

Guidance literature:

With acetic acid; urea; In water; at 25 - 100 ℃;

DOI:10.1134/S1070428017070028

upstream raw materials:

bicyclo[3.3.1]nonane

bicyclo[3.3.1]nonane-3,7-dione

Downstream raw materials:

1-Hydroxybicyclo<3.3.1>nonane

Refernces