BICYCLO[3.3.1]NONANE-3,7-DIONE

Base Information

• Chemical Name: BICYCLO[3.3.1]NONANE-3,7-DIONE
• CAS No.: 770-15-0
• Molecular Formula: C9H12O2
• Molecular Weight: 152.193
• Hs Code.: 2914299000
• Mol file: 770-15-0.mol

Synonyms:BICYCLO[3.3.1]NONANE-3,7-DIONE

Chemical Property of BICYCLO[3.3.1]NONANE-3,7-DIONE

Chemical Property:

• Vapor Pressure: 0.00311mmHg at 25°C
• Melting Point: 240 °C (decomp)
• Refractive Index: 1.507
• Boiling Point: 283.7°C at 760 mmHg
• Flash Point: 105.6°C
• PSA: 34.14000
• Density: 1.138g/cm³
• LogP: 1.33470
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

98%Min ^*data from raw suppliers

Bicyclo[3.3.1]nonane-3,7-dione ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of BICYCLO[3.3.1]NONANE-3,7-DIONE

There total 3 articles about BICYCLO[3.3.1]NONANE-3,7-DIONE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

adamantane (281-23-2) → 2-Adamantanone (700-58-3) + Bicyclo<3.3.1>nonan-3,7-dion (770-15-0) + 1-adamanthanol (768-95-6) + 1-adamantanol (700-57-2)

Guidance literature:

With oxygen; titanium(IV) oxide; In water; acetonitrile; for 3h; Irradiation;

DOI:10.1016/S0040-4020(03)01092-5

Reference yield: 14.0%

adamantane (281-23-2) + acetonitrile (75-05-8,26809-02-9) → Bicyclo<3.3.1>nonan-3,7-dion (770-15-0) + 1-adamantanecarbonitrile (23074-42-2) + N-(1-adamantyl)acetamide (880-52-4) + 1-acetyladamantane (1660-04-4)

Guidance literature:

With titanium(IV) oxide; silver sulfate; for 15h; Irradiation;

DOI:10.1016/S0040-4020(03)01092-5

Reference yield:

1,3-dibromoadamantane (876-53-9) → bicyclo[3.3.1]nonane-3,7-dione (770-15-0)

Guidance literature:

Multi-step reaction with 2 steps

1: NaOH / dioxane / 180 °C

2: KMnO₄, dodecahydro-dibenzo-18-crown-6

With perhydrodibenzo-18-crown-6; sodium hydroxide; potassium permanganate; In 1,4-dioxane;

upstream raw materials:

adamantane

acetonitrile

1,3-dibromoadamantane

Downstream raw materials:

1-Hydroxybicyclo<3.3.1>nonane

1-nitroxybicyclo<3.3.1>nonane

bicyclo[3.3.1]nonane

Refernces