P-Trimethylsilyl styrene

Base Information

• Chemical Name: P-Trimethylsilyl styrene
• CAS No.: 1009-43-4
• Molecular Formula: C11H16Si
• Molecular Weight: 176.334
• Hs Code.: 2931900090
• Mol file: 1009-43-4.mol

Synonyms:Silane,(4-ethenylphenyl)trimethyl- (9CI);Silane, trimethyl(p-vinylphenyl)-(6CI,7CI,8CI);4-Trimethylsilylstyrene;Trimethyl(4-vinylphenyl)silane;Trimethyl(p-vinylphenyl)silane;p-(Trimethylsilyl)styrene;

Chemical Property of P-Trimethylsilyl styrene

Chemical Property:

• Refractive Index: 1.525
• Boiling Point: 226.3 °C at 760 mmHg
• Flash Point: 76.1 °C
• PSA: 0.00000
• Density: 0.86 g/cm³
• LogP: 2.87480

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trimethyl(4-vinylphenyl)silane (stabilized with TBC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Use Description: P-Trimethylsilyl styrene, a chemical compound, finds applications in various fields due to its unique properties. In the realm of organic synthesis and materials science, it serves as a valuable building block for the modification of polymers and the development of specialized materials with enhanced properties. In the field of pharmaceuticals and biotechnology, this compound can be employed as a reagent for the synthesis of specific drug molecules and as a protective group for sensitive functional groups in drug development. Additionally, in the electronics industry, P-Trimethylsilyl styrene can be used in the production of silicon-based materials and as a precursor for the fabrication of microelectronic devices, contributing to the advancement of technology. Its versatility as a chemical building block underscores its significance in organic chemistry, materials science, pharmaceuticals, biotechnology, and electronics, playing crucial roles in advancing research and innovation in these fields.

Technology Process of P-Trimethylsilyl styrene

There total 24 articles about P-Trimethylsilyl styrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

n-butyllithium (109-72-8,29786-93-4) + 1-bromo-4-ethenyl-benzene (2039-82-9) → 4-(trimethylsilyl)styrene (1009-43-4)

Guidance literature:

With chloro-trimethyl-silane; In tetrahydrofuran; hexane; ethyl acetate;

Reference yield: 92.0%

1-bromo-4-ethenyl-benzene (2039-82-9) + sodium trimethylsilyldimethylsilanolate → 4-(trimethylsilyl)styrene (1009-43-4)

Guidance literature:

With MePhos Pd G₄; In 1,2-dichloro-ethane; at 50 ℃;

DOI:10.1021/acscatal.1c02733

Reference yield: 82.0%

chloro-trimethyl-silane (75-77-4) + 1-bromo-4-ethenyl-benzene (2039-82-9) → 4-(trimethylsilyl)styrene (1009-43-4)

Guidance literature:

With magnesium; In tetrahydrofuran; for 2h; ultarsonic bath 47 kHz, 300 W;

DOI:10.1016/S0022-328X(03)00053-6

upstream raw materials:

4-vinylbenzyl chloride

1-bromo-4-(trimethylsilyl)benzene

(RS)-1-(4-trimethylsilylphenyl)ethanol

(ph-4-vi)SiCl₃

Downstream raw materials:

trimethyl-(4-oxiranyl-phenyl)-silane

C₁₁H₁₅Cl₂OPSi

(3S,5R)-3,5-Dimethyl-4-[3-(4-trimethylsilanyl-phenyl)-cyclobutyl]-morpholine

(3S,5R)-3,5-Dimethyl-4-[3-(4-trimethylsilanyl-phenyl)-cyclobutyl]-morpholine

Refernces

• 1、 Pike. "-". . p. 577. Retrieved 1959.
• 2、 Zhang, Xu,Wang, Zhen-Yu,Wang, Xing,Xu, Hui,Dai, Hui-Xiong. "Functionalized styrene synthesis via palladium-catalyzed C[sbnd]C cleavage of aryl ketones". supporting information. . Retrieved 2022/03/31.