Benz[b]indolo[2,3-d][1]benzazepine, 5,10-dihydro-5-phenyl-

Base Information

• Chemical Name: Benz[b]indolo[2,3-d][1]benzazepine, 5,10-dihydro-5-phenyl-
• CAS No.: 1799295-84-3
• Molecular Formula: C₂₆H₁₈N₂
• Molecular Weight: 358.442
• Mol file: 1799295-84-3.mol

Synonyms:

Chemical Property of Benz[b]indolo[2,3-d][1]benzazepine, 5,10-dihydro-5-phenyl-

Chemical Property:

• Boiling Point: 614.7±28.0 °C(Predicted)
• PKA: 1.92±0.20(Predicted)
• Density: 1.21±0.1 g/cm3(Predicted)

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benz[b]indolo[2,3-d][1]benzazepine, 5,10-dihydro-5-phenyl-

There total 5 articles about Benz[b]indolo[2,3-d][1]benzazepine, 5,10-dihydro-5-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

10,11-dihydro-5H-dibenzo[b,f]azepin-10-one (21737-58-6) + 1,1-Diphenylhydrazine (530-50-7) → C26H18N2 (1799295-84-3)

Guidance literature:

With acetic acid; at 120 ℃; for 12h; Inert atmosphere;

Reference yield:

dibenzoazepine (256-96-2) → C26H18N2 (1799295-84-3)

Guidance literature:

Multi-step reaction with 5 steps

1: toluene / 2 h / 80 °C / Inert atmosphere

2: 3-chloro-benzenecarboperoxoic acid; sodium hypochlorite; silica gel / acetonitrile / 2 h / 80 °C / Inert atmosphere

3: lithium iodide / chloroform / 1 h / 60 °C / Inert atmosphere

4: potassium hydroxide / ethylene glycol / 6 h / 200 °C / Inert atmosphere

5: acetic acid / 12 h / 120 °C / Inert atmosphere

With sodium hypochlorite; silica gel; acetic acid; 3-chloro-benzenecarboperoxoic acid; potassium hydroxide; lithium iodide; In chloroform; ethylene glycol; toluene; acetonitrile;

Reference yield:

N-acetyl iminostilbene (19209-60-0) → C26H18N2 (1799295-84-3)

Guidance literature:

Multi-step reaction with 4 steps

1: 3-chloro-benzenecarboperoxoic acid; sodium hypochlorite; silica gel / acetonitrile / 2 h / 80 °C / Inert atmosphere

2: lithium iodide / chloroform / 1 h / 60 °C / Inert atmosphere

3: potassium hydroxide / ethylene glycol / 6 h / 200 °C / Inert atmosphere

4: acetic acid / 12 h / 120 °C / Inert atmosphere

With sodium hypochlorite; silica gel; acetic acid; 3-chloro-benzenecarboperoxoic acid; potassium hydroxide; lithium iodide; In chloroform; ethylene glycol; acetonitrile;

upstream raw materials:

dibenzoazepine

N-acetyl iminostilbene

5-acetyl-10,11-epoxy-10,11-dihydro-5H-dibenzazepine

5-acetyl-10-oxo-10,11-dihydro-5H-dibenzazepine

Refernces

• 1、 -. "ORGANIC COMPOUNDS AND ORGANIC ELECTRO LUMINESCENCE DEVICE COMPRISING THE SAME". Paragraph 0094; 0095; 0096; 0097. . Retrieved 2016/10/08.