hydrido(η-ethylcyclopentadienyl)bis(triphenylphosphine)iridium(III) hexafluoroantimonate

Base Information

• Chemical Name: hydrido(η-ethylcyclopentadienyl)bis(triphenylphosphine)iridium(III) hexafluoroantimonate
• CAS No.: 106864-49-7
• Molecular Formula: C₄₃H₄₀IrP₂*F₆Sb
• Molecular Weight: 1046.7
• Mol file: 106864-49-7.mol

Synonyms:

Chemical Property of hydrido(η-ethylcyclopentadienyl)bis(triphenylphosphine)iridium(III) hexafluoroantimonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hydrido(η-ethylcyclopentadienyl)bis(triphenylphosphine)iridium(III) hexafluoroantimonate

There total 4 articles about hydrido(η-ethylcyclopentadienyl)bis(triphenylphosphine)iridium(III) hexafluoroantimonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

{IrH2(acetone)2(PPh3)2}SbF6 (110077-68-4,89509-77-3) + 1-ethylcyclopentene (2146-38-5) → hydrido(η-ethylcyclopentadienyl)bis(triphenylphosphine)iridium(III) hexafluoroantimonate (106864-49-7)

Guidance literature:

In 1,2-dichloro-benzene; refluxed for 6 h under inert atmosphere; cooled, evapd., residue recrystd. from CH2Cl2-Et2O;

DOI:10.1021/om00147a003

Reference yield: 36.0%

{IrH2(acetone)2(PPh3)2}SbF6 (110077-68-4,89509-77-3) + ethylcyclopentane (1640-89-7) → hydrido(η-ethylcyclopentadienyl)bis(triphenylphosphine)iridium(III) hexafluoroantimonate (106864-49-7)

Guidance literature:

In neat (no solvent); Ir-complex (grounded to a fine powder) was heated with ethylcyclopentane in a sealed pressure vessel magnetically stirred under inert atmosphere; volatiles removed in vacuo, residue was analysed by (1)H NMR spectroscopy;

DOI:10.1021/om00147a003

Reference yield:

{IrH2(acetone)2(PPh3)2}SbF6 (110077-68-4,89509-77-3) → hydrido(η-ethylcyclopentadienyl)bis(triphenylphosphine)iridium(III) hexafluoroantimonate (106864-49-7)

Guidance literature:

With ethylcyclopentadienes; In dichloromethane; 30 min, 40°C, inert atmosphere; elem. anal.;

DOI:10.1021/om00147a003

upstream raw materials:

{IrH₂(acetone)2(PPh₃)2}SbF₆

3-ethylcyclopentene

1-ethylcyclopentene

ethylcyclopentane

Refernces