[5-(3-amino-4-nitrophenyl)-10,15,20-triphenyl-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]copper

Base Information

• Chemical Name: [5-(3-amino-4-nitrophenyl)-10,15,20-triphenyl-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]copper
• CAS No.: 960590-21-0
• Molecular Formula: C₄₄H₂₈CuN₆O₂
• Molecular Weight: 736.291
• Mol file: 960590-21-0.mol

Synonyms:

Chemical Property of [5-(3-amino-4-nitrophenyl)-10,15,20-triphenyl-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]copper

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [5-(3-amino-4-nitrophenyl)-10,15,20-triphenyl-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]copper

There total 1 articles about [5-(3-amino-4-nitrophenyl)-10,15,20-triphenyl-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]copper which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

[5-(4-nitrophenyl)-10,15,20-triphenylporphyrinato]copper(II) (202007-69-0) + N,N,N-trimethylhydrazinium iodide (3288-80-0) → [5-(3-amino-4-nitrophenyl)-10,15,20-triphenyl-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]copper (960590-21-0)

Guidance literature:

With potassium hydroxide; In dimethyl sulfoxide; to stirred suspn. of powdered KOH and complex hydrazinium was added at 60-70°C under Ar, after 4 h additional KOH and hydrazinium were added, reaction was stirred for 4-6 h; mixt. was poured into 3% aq. HCl contg. ice, soln. was extd. with CHCl3,combined organic layer washed with H2O, dried (Na2SO4), evapd., residue chromd. (silica gel, CHCl3/hexane 2:1, then 3:1, then CHCl3); UV, MAS;

DOI:10.1002/hlca.200790207

upstream raw materials:

[5-(4-nitrophenyl)-10,15,20-triphenylporphyrinato]copper(II)

N,N,N-trimethylhydrazinium iodide

Refernces