Dibromo zinc bis[3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl]porphyrin

Base Information

• Chemical Name: Dibromo zinc bis[3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl]porphyrin
• CAS No.: 1051971-72-2
• Molecular Formula: C46H46Br2N4O8Zn
• Molecular Weight: 1008.09
• Mol file: 1051971-72-2.mol

Synonyms:2,7-Dibromo-9,9'-spiro-bifluorene

Chemical Property of Dibromo zinc bis[3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl]porphyrin

Chemical Property:

• Appearance/Colour: solid
• PSA: 96.64000
• LogP: 5.16030

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Dibromo zinc bis[3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl]porphyrin

There total 8 articles about Dibromo zinc bis[3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl]porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

N-Bromosuccinimide (128-08-5) + 5,15-bis-(3-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}phenyl)porphyrin zinc (1051971-71-1) → C46H46Br2N4O8Zn (1051971-72-2)

Guidance literature:

With pyridine; In chloroform; for 0.75h;

Reference yield: 99.0%

5,15-bis(3-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)phenyl)porphyrinatozinc (1051971-71-1) → Zn((MeO(CH2CH2O)3C6H4)2(Br)2C20H8N2) (1051971-72-2)

Guidance literature:

With pyridine; N-Bromosuccinimide; In chloroform; for 0.75h;

DOI:10.1039/b814789b

Reference yield: 99.0%

N-Bromosuccinimide (128-08-5) + 5,15-bis(3-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)phenyl)porphyrinatozinc (1051971-71-1) → Zn((MeO(CH2CH2O)3C6H4)2(Br)2C20H8N2) (1051971-72-2)

Guidance literature:

In pyridine; chloroform; (inert atm.); addn. of soln. of bromosuccinimide in CHCl3 and pyridine to soln. of porphyrin deriv. in pyridine and CHCl3 for 30 min, stirring for 15 min; addn. of acetone, evapn., chromy. (silica, 99:1 CH2Cl2/methanol), NMR and MALDI;

DOI:10.1039/b814789b

upstream raw materials:

N-Bromosuccinimide

5,15-bis-(3-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}phenyl)porphyrin zinc

3-(2-[2-(2-methoxy-ethoxy)-ethoxy]-ethoxy)-benzaldehyde

2-(2-(2-methoxyethoxy)ethoxy)ethyl p-toluenesulfonate

Downstream raw materials:

C₆₆H₈₅BrN₄O₈SiZn

Zn((MeO(CH₂CH₂O)3C₆H₄)2(THSCC)2C₂₀H₈N₂)

Zn((MeO(CH₂CH₂O)3C₆H₄)2(THSCC)(Br)C₂₀H₈N₂)

Refernces

• 1、 -. "PORPHYRIN COMPOUNDS". Page/Page column 25-26; 29; 31; 33. . Retrieved 2008/12/04.