POLYACENAPHTHYLENE

Base Information

• Chemical Name: POLYACENAPHTHYLENE
• CAS No.: 25036-01-5
• Molecular Formula: C₁₂H₈
• Molecular Weight: 152.196
• Hs Code.: 39029090
• Mol file: 25036-01-5.mol

Synonyms:

Chemical Property of POLYACENAPHTHYLENE

Chemical Property:

• Vapor Pressure: 0.0022mmHg at 25°C
• Melting Point: 291?°C (dec.)(lit.)

Purity/Quality:

98%min ^*data from raw suppliers

Polyacenaphthylene average M ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi:Irritant
• Statements: R36/37/38:
• Safety Statements: 24/25

MSDS Files:

Useful:

Technology Process of POLYACENAPHTHYLENE

There total 187 articles about POLYACENAPHTHYLENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

acenaphthene (83-32-9) + chloranil (118-75-2) → 2,3,5,6-tetrachlorobenzene-1,4-diol (87-87-6) + acenaphthylene (208-96-8,25036-01-5)

Guidance literature:

In benzene; for 18h; Irradiation;

DOI:10.1021/ja00214a043

Reference yield: 41.0%

acenaphthene quinone (82-86-0) → 1-acenaphthenol (6306-07-6) + acenaphthene (83-32-9) + acenaphthylene (208-96-8,25036-01-5)

Guidance literature:

With samarium diiodide; water; In tetrahydrofuran; at 20 ℃; for 0.00277778h;

DOI:10.1248/cpb.53.1017

Reference yield: 31.0%

acenaphthene quinone (82-86-0) → decacyclene (191-48-0) + 1-acenaphthenol (6306-07-6) + acenaphthene (83-32-9) + acenaphthylene (208-96-8,25036-01-5)

Guidance literature:

bis(η⁶-biphenyl)titanium(0); In toluene; at 110 ℃; for 2h; Further byproducts given;

DOI:10.1055/s-1997-3209

upstream raw materials:

N-Bromosuccinimide

potassium acetate

acenaphthene

acetic acid

Downstream raw materials:

7,12-diphenyl-(6br,12ac)-6b,7,12,12a-tetrahydro-7ξ,12ξ-epoxido-benzo[k]fluoranthene

(7,12-diphenyl)benzofluoranthene

(6brH.10acH)-6b.7.10.10a-tetrahydro-fluoranthene

9-phenyl-6b,9a-dihydro-acenaphtho[1,2-d]isoxazole

Refernces

• 1、 Bobkova,Stokolos,Garifullin. "Mechanisms of Heptane Degradation and Product Formation in Microwave Discharge". . p. 336 - 340. Retrieved 2019/08/15.
• 2、 -. "RECORDING MATERIAL AND OPTICAL INFORMATION RECORDING MEDIUM". . . Retrieved 2016/06/01.