Cyclohexyltrimethylsilane

Base Information

• Chemical Name: Cyclohexyltrimethylsilane
• CAS No.: 10151-74-3
• Molecular Formula: C9H20Si
• Molecular Weight: 156.343
• DSSTox Substance ID: DTXSID701310051
• Nikkaji Number: J1.588.041D
• Mol file: 10151-74-3.mol

Synonyms:cyclohexyltrimethylsilane;(trimethylsilyl)cyclohexane;10151-74-3;Cyclohexyltrirnethylsilane;OOHJXNKKHVHEFP-UHFFFAOYSA-N;DTXSID701310051

Chemical Property of Cyclohexyltrimethylsilane

Chemical Property:

• PSA: 0.00000
• LogP: 3.65890
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 156.133427172
• Heavy Atom Count: 10
• Complexity: 95.8

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)C1CCCCC1

Technology Process of Cyclohexyltrimethylsilane

There total 9 articles about Cyclohexyltrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

cyclohexa-2,4-dien-1-yltrimethylsilane + cyclohexene (110-83-8) → cyclohexyl-trimethyl-silane (10151-74-3)

Guidance literature:

With tris(pentafluorophenyl)borate; In toluene; at 50 ℃; for 23h; Sealed tube; Inert atmosphere;

DOI:10.1039/c7cc06195a

Reference yield: 84.0%

trimethylphenylsilane (768-32-1) → cyclohexyl-trimethyl-silane (10151-74-3)

Guidance literature:

With hydrogen; Rh on carbon; In cyclohexane; at 55 ℃; for 4h;

DOI:10.1021/jo00327a013

Reference yield: 81.0%

chloro-cyclohexyl-dimethylsilane (71864-47-6) + methyl iodide (74-88-4) → cyclohexyl-trimethyl-silane (10151-74-3)

Guidance literature:

With magnesium; In diethyl ether; at 0 - 20 ℃; for 8h;

DOI:10.1021/acs.joc.6b02917

upstream raw materials:

trimethylphenylsilane

dibromo-cyclohexyl-methyl-silane

methyl iodide

chloro-trimethyl-silane

Downstream raw materials:

1,1,3,3-tetramethyl-1,3-dicyclohexyldisiloxane

dimethyl(cyclohexyl)methoxysilane

cyclohexanol

Refernces

• 1、 Bennet et al.. "". . p. 79. Retrieved 1970.
• 2、 Torigoe, Takeru,Ohmura, Toshimichi,Suginome, Michinori. "Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)-H Borylation at the Methyl Group on Silicon". . p. 2943 - 2956. Retrieved 2017/03/23.