Thallium, bromodiphenyl-

Base Information

• Chemical Name: Thallium, bromodiphenyl-
• CAS No.: 10192-61-7
• Molecular Formula: C12H10BrTl
• Molecular Weight: 438.498
• DSSTox Substance ID: DTXSID30398861
• Wikidata: Q82201091
• Mol file: 10192-61-7.mol

Synonyms:Thallium, bromodiphenyl-;BROMODIPHENYLTHALLIUM;10192-61-7;diphenylthallium bromide;DTXSID30398861;AKOS024433651

Chemical Property of Thallium, bromodiphenyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 437.97102
• Heavy Atom Count: 14
• Complexity: 142

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Tl](C2=CC=CC=C2)Br

Technology Process of Thallium, bromodiphenyl-

There total 11 articles about Thallium, bromodiphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

thallium(I) bromide + phenylboronic acid (98-80-6) → diphenyl (monobromo) thallium (10192-61-7)

Guidance literature:

With Br₂; In water; Br2 was added with stirring to suspn. of TlBr in water until clear soln.was obtained; excess Br2 was removed (vac.); soln. was slowly added to suspn. of PhB(OH)2 in water; mixt. was refluxed for 5 h; cooled; filtered; washed (water); dried (vac.);

DOI:10.1016/S0020-1693(02)01433-0

Reference yield:

2,3,4,5,6-pentafluorophenylmagnesium bromide (879-05-0) → diphenyl (monobromo) thallium (10192-61-7)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether

2: diethyl ether

In diethyl ether;

DOI:10.1039/JR9650003411

Reference yield:

triphenylbismuthane (603-33-8) + Bromo-bis-(pentafluorphenyl)-thallium(III) (1735-62-2) → diphenyl (monobromo) thallium (10192-61-7)

Guidance literature:

In diethyl ether; 2 h;

upstream raw materials:

triphenylbismuthane

Bromo-bis-(pentafluorphenyl)-thallium(III)

sodium tetraphenyl borate

diphenylmercury(II)

Downstream raw materials:

iodobenzene

tetraphenyltin(IV)

thallium(III) triphenyl

[Tl(C₆H₅)2(CH₃OC₆H₄CHNNC(S)NH₂)]

Refernces

• 1、 Lobana, Tarlok S.,Casas, José S.,Casti?eiras, Alfonso,García-Tasende, María S.,Sánchez, Agustín,Sordo, José. "Diphenylthallium(III) thiosemicarbazonates: Flexibility of coordination in the solid state and polymorphism in chloroform solution". . p. 23 - 32. Retrieved 2008/10/08.