Bromo[bis(pentafluorophenyl)]thallane

Base Information

• Chemical Name: Bromo[bis(pentafluorophenyl)]thallane
• CAS No.: 1735-62-2
• Molecular Formula: C12BrF10Tl
• Molecular Weight: 618.403
• DSSTox Substance ID: DTXSID30499408
• Mol file: 1735-62-2.mol

Synonyms:Bromo[bis(pentafluorophenyl)]thallane;1735-62-2;DTXSID30499408;bis(pentafluorophenyl) thallium(iii) bromide

Chemical Property of Bromo[bis(pentafluorophenyl)]thallane

Chemical Property:

• PSA: 0.00000
• LogP: 2.34680
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 2
• Exact Mass: 617.87680
• Heavy Atom Count: 24
• Complexity: 376

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1(=C(C(=C(C(=C1F)F)[Tl](C2=C(C(=C(C(=C2F)F)F)F)F)Br)F)F)F

Technology Process of Bromo[bis(pentafluorophenyl)]thallane

There total 2 articles about Bromo[bis(pentafluorophenyl)]thallane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

2,3,4,5,6-pentafluorophenylmagnesium bromide (879-05-0) + thallium (III) chloride (13453-32-2) → thallium(III)(C6F5)3 (1109-16-6) + Bromo-bis-(pentafluorphenyl)-thallium(III) (1735-62-2)

Guidance literature:

In toluene; addition of C6F5MgBr (in ether) to a solution of TlCl3 in boiling toluene;;

Reference yield: 45.0%

2,3,4,5,6-pentafluorophenylmagnesium bromide (879-05-0) + thallium (III) chloride (13453-32-2) → Bromo-bis-(pentafluorphenyl)-thallium(III) (1735-62-2)

Guidance literature:

In diethyl ether; addition of TlCl3 to C6F5MgBr (molar ratio 3 : 8), 1.5 hours;;

Reference yield: 90.0%

NBu4{(C6F5)Br(aurate(I))} + Bromo-bis-(pentafluorphenyl)-thallium(III) (1735-62-2) → {(n-C4H9)4N}{(C6F5)3AuBr}

Guidance literature:

In benzene; stirring for 5 h at 20°C;

DOI:10.1016/S0022-328X(00)84425-3

upstream raw materials:

2,3,4,5,6-pentafluorophenylmagnesium bromide

thallium (III) chloride

Downstream raw materials:

diphenyl (monobromo) thallium

thallium(I) fluoride

bromopentafluorobenzene

decafluorobiphenyl