methyl-(2-nitro-phenyl)-sulfoxide

Base Information

• Chemical Name: methyl-(2-nitro-phenyl)-sulfoxide
• CAS No.: 132016-28-5
• Molecular Formula: C₇H₇NO₃S
• Molecular Weight: 185.203
• Mol file: 132016-28-5.mol

Synonyms:

Chemical Property of methyl-(2-nitro-phenyl)-sulfoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl-(2-nitro-phenyl)-sulfoxide

There total 5 articles about methyl-(2-nitro-phenyl)-sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

methyl 2-nitrophenyl sulfide (3058-47-7) → methyl-(2-nitro-phenyl)-sulfoxide (132016-28-5,139562-08-6,19199-94-1)

Guidance literature:

With 2-phenyl-1,2-benzoisoselenazol-3(2H)-one; dihydrogen peroxide; In methanol; water; at 20 ℃; for 48h;

DOI:10.1080/00397919608003617

Reference yield: 55.0%

2-(2-Nitro-benzenesulfinyl)-pyridine 1-oxide (125556-93-6) + methyl iodide (74-88-4) → methyl-(2-nitro-phenyl)-sulfoxide (132016-28-5,139562-08-6,19199-94-1)

Guidance literature:

With sodium ethanolate; In acetonitrile; Ambient temperature;

Reference yield: 9.0%

dimethylsulfone (67-71-0) + 2-nitro-aniline (88-74-4) → methyl-(2-nitro-phenyl)-sulfoxide (132016-28-5,139562-08-6,19199-94-1) + nitrobenzene (98-95-3,26969-40-4) + 1,2-Dinitrobenzene (528-29-0) + 2-hydroxynitrobenzene (88-75-5,78813-12-4)

Guidance literature:

With tert.-butylnitrite; copper; at 60 ℃; for 1.5h; Further byproducts given;

DOI:10.1016/0040-4020(96)00331-6

upstream raw materials:

methyl 2-nitrophenyl sulfide

2-(2-Nitro-benzenesulfinyl)-pyridine 1-oxide

methyl iodide

dimethylsulfone

Downstream raw materials:

sodium o-nitrophenate

C₇H₈N₂O₃S

Refernces

• 1、 Fakhri, Hanieh,Mahjoub, Alireza,Maridiroosi, Anasheh,Nejat, Razieh. "Fabrication of molybdenum-substituted tungstophosphoric acid immobilized onto functionalized graphene oxide: Visible light-induced photocatalyst for selective oxidation of sulfides to sulfoxides". . . Retrieved 2020/12/17.
• 2、 Pramanik, Mukund M. D.,Rastogi, Namrata. "Visible light catalyzed methylsulfoxidation of (het)aryl diazonium salts using DMSO". supporting information. p. 8557 - 8560. Retrieved 2016/07/13.