Hydroxymethyl radical

Base Information

• Chemical Name: Hydroxymethyl radical
• CAS No.: 2597-43-5
• Molecular Formula: CH3 O
• Molecular Weight: 31.0342
• DSSTox Substance ID: DTXSID40180633
• Nikkaji Number: J371.065C
• Mol file: 2597-43-5.mol

Synonyms:Hydroxymethyl radical;2597-43-5;CH2OH;DTXSID40180633

Chemical Property of Hydroxymethyl radical

Chemical Property:

• PSA: 20.23000
• LogP: -0.51450
• XLogP3: -0.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 31.018389715
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [CH2]O

Technology Process of Hydroxymethyl radical

There total 16 articles about Hydroxymethyl radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl radical (2229-07-4) → methanol (67-56-1) + methylene (2465-56-7) + methoxyl radical (2143-68-2) + hydroxymethyl radical (2597-43-5)

Guidance literature:

With hydroxyl; at 989.84 ℃; under 972.865 Torr; Further Variations:; Temperatures; Pressures; Kinetics;

DOI:10.1002/kin.20334

Reference yield:

methanol (67-56-1) → methyl radical (2229-07-4) + methylene (2465-56-7) + hydroxymethyl radical (2597-43-5)

Guidance literature:

at 1226.9 - 1476.9 ℃; Kinetics; Mechanism;

Reference yield:

methanol (67-56-1) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + methyl radical (2229-07-4) + methylene (2465-56-7) + methoxyl radical (2143-68-2) + hydroxycarbene (19710-56-6,63541-95-7,81434-73-3,86549-47-5,96026-45-8,99663-53-3) + hydroxymethyl radical (2597-43-5)

Guidance literature:

Thermodynamic data; Irradiation;

DOI:10.1016/0584-8539(87)80101-0

upstream raw materials:

methanol

C₅H₉O₂

dihydroxymethyl radical

polyethylene glycol

Downstream raw materials:

C₈H₁₀NO₆S

methanol

formaldehyd

methyl nitrite

Refernces

• 1、 Góbi, Sándor,Crandall, Parker B.,Maksyutenko, Pavlo,F?rstel, Marko,Kaiser, Ralf I.. "Accessing the Nitromethane (CH3NO2) Potential Energy Surface in Methanol (CH3OH)-Nitrogen Monoxide (NO) Ices Exposed to Ionizing Radiation: An FTIR and PI-ReTOF-MS Investigation". . p. 2329 - 2343. Retrieved 2018/03/21.
• 2、 Orlando, John J.,Tyndall, Geoffrey S.,Bilde, Merete,Ferronato, Corinne,Wallington, Timothy J.,Vereecken, Luc,Peeters, Jozef. "Laboratory and theoretical study of the oxy radicals in the OH- and Cl-initiated oxidation of ethene". . p. 8116 - 8123. Retrieved 2007/10/03.