Technology Process of 1-benzene-sulfonyl-2α,7α-20α,19-tetrahydro-10-deoxysarpagine
There total 6 articles about 1-benzene-sulfonyl-2α,7α-20α,19-tetrahydro-10-deoxysarpagine which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
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![(2S,3S)-12-Benzenesulfonyl-3-ethyl-1,3,4,7,7a,12,12a,12b-octahydro-2H,6H-2,6-methano-indolo[2,3-a]quinolizine-13-carbaldehyde](/Databaselist/images/loading.webp)
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82510-86-9
(2S,3S)-12-Benzenesulfonyl-3-ethyl-1,3,4,7,7a,12,12a,12b-octahydro-2H,6H-2,6-methano-indolo[2,3-a]quinolizine-13-carbaldehyde
- Guidance literature:
-
With
sodium tetrahydroborate;
In
methanol;
for 6h;
Ambient temperature;
DOI:10.1016/0040-4020(82)80007-0
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 509 mg / NaOMe / methanol / 12 h / 50 °C
2: pyridine
3: KCN, pyruvate de sodium, O2 / methanol / Irradiation; in the presence of rose bengale
4: 20 percent / NaOH / dioxane; H2O / 4 h / Heating
5: 30 mg / NaBH4 / methanol / 6 h / Ambient temperature
With
pyridine; potassium cyanide; sodium hydroxide; sodium tetrahydroborate; sodium pyruvate; oxygen; sodium methylate;
In
1,4-dioxane; methanol; water;
DOI:10.1016/0040-4020(82)80007-0
- Guidance literature:
-
Multi-step reaction with 4 steps
1: pyridine
2: KCN, pyruvate de sodium, O2 / methanol / Irradiation; in the presence of rose bengale
3: 20 percent / NaOH / dioxane; H2O / 4 h / Heating
4: 30 mg / NaBH4 / methanol / 6 h / Ambient temperature
With
pyridine; potassium cyanide; sodium hydroxide; sodium tetrahydroborate; sodium pyruvate; oxygen;
In
1,4-dioxane; methanol; water;
DOI:10.1016/0040-4020(82)80007-0
