platinum(II)(6,6'-diphenyl-2,2'-bipyridine-H)Cl

Base Information

• Chemical Name: platinum(II)(6,6'-diphenyl-2,2'-bipyridine-H)Cl
• CAS No.: 688349-49-7
• Molecular Formula: C₂₂H₁₅ClN₂Pt
• Molecular Weight: 537.907
• Mol file: 688349-49-7.mol

Synonyms:

Chemical Property of platinum(II)(6,6'-diphenyl-2,2'-bipyridine-H)Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of platinum(II)(6,6'-diphenyl-2,2'-bipyridine-H)Cl

There total 1 articles about platinum(II)(6,6'-diphenyl-2,2'-bipyridine-H)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

potassium tetrachloroplatinate(II) (10025-99-7) + 6,6’-diphenyl-2,2’-bipyridine (85575-95-7) → platinum(II)(6,6'-diphenyl-2,2'-bipyridine-H)Cl (688349-49-7)

Guidance literature:

With HCl; In water; to Pt-compd. in H2O added under vigorous stirring pyridine-compd. and 2 N HCl, heated to reflux for 5 days, cooled; filtered, washed with H2O, EtOH and Et2O, recrystallised from CH2Cl2/Et2O, elem. anal.;

DOI:10.1016/j.jorganchem.2009.07.034

Reference yield: 90.0%

silver tetrafluoroborate (14104-20-2) + platinum(II)(6,6'-diphenyl-2,2'-bipyridine-H)Cl (688349-49-7) + triphenylphosphine (603-35-0) → (platinum(II)(6,6'-diphenyl-2,2'-bipyridine-H)(P(C6H5)3))(BF4) (1197358-73-8)

Guidance literature:

In acetone; byproducts: AgCl; AgBF4 added under vigorous stirring to Pt-compd. in acetone, AgCl filtered, solid P(C6H5)3 (molar ratio 1:1) added, stirred at room temp. for 3 h; concentrated, treated with n-hexane, filtered, washed with n-hexane, elem. anal.;

DOI:10.1016/j.jorganchem.2009.07.034

Reference yield: 60.0%

silver tetrafluoroborate (14104-20-2) + carbon monoxide (201230-82-2) + platinum(II)(6,6'-diphenyl-2,2'-bipyridine-H)Cl (688349-49-7) → (platinum(II)(6,6'-diphenyl-2,2'-bipyridine-H)(CO))(BF4) (1197358-69-2)

Guidance literature:

In acetone; byproducts: AgCl; AgBF4 added under vigorous stirring to Pt-compd. in acetone, AgCl filtered, CO bubbled into the solution at room temp. for 12 h; concentrated, treated with n-hexane, filtered, washed with n-hexane, elem. anal.;

DOI:10.1016/j.jorganchem.2009.07.034

upstream raw materials:

potassium tetrachloroplatinate(II)

6,6’-diphenyl-2,2’-bipyridine

Downstream raw materials:

(platinum(II)(6,6'-diphenyl-2,2'-bipyridine-H)(CO))(BF₄)

(platinum(II)(6,6'-diphenyl-2,2'-bipyridine-H)(P(C₆H₅)3))(BF₄)

Refernces