TRIHEXYL(TETRADECYL)PHOSPHONIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE

Base Information

• Chemical Name: TRIHEXYL(TETRADECYL)PHOSPHONIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE
• CAS No.: 460092-03-9
• Deprecated CAS: 1001396-46-8
• Molecular Formula: C₂F₆NO₄S₂*C₃₂H₆₈P
• Molecular Weight: 764.014
• European Community (EC) Number: 629-283-4
• NSC Number: 747251
• DSSTox Substance ID: DTXSID1049304
• ChEMBL ID: CHEMBL3183021
• Mol file: 460092-03-9.mol

Synonyms:460092-03-9;Trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)amide;Trihexyl(tetradecyl)phosphonium bis(trifluoromethanesulfonyl)amide;DTXSID1049304;Trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)imide;bis(trifluoromethylsulfonyl)azanide;trihexyl(tetradecyl)phosphanium;TRIHEXYL(TETRADECYL)PHOSPHONIUM BIS((TRIFLUOROMETHYL)SULFONYL)AMIDE;Phosphonium, trihexyltetradecyl-, salt with 1,1,1-trifluoro-N-((trifluoromethyl)sulfonyl)methanesulfonamide (1:1);Phosphonium, trihexyltetradecyl-, salt with 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide (1:1);MFCD04117695;SCHEMBL451878;CHEMBL3183021;DTXCID7029160;HYNYWFRJHNNLJA-UHFFFAOYSA-N;Tetradecyltrihexylphosphonium bis(trifluoromethylsulfonyl)amide;Tox21_202614;NSC747251;AKOS015913634;AT25631;NSC 747251;NSC-747251;NCGC00260162-01;CAS-460092-03-9;CS-0452752;Trihexyl(tetradecyl)Phosphonium Bis (Trifluoromethylsulfonylmide);Trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)amide, >=95.0%

Chemical Property of TRIHEXYL(TETRADECYL)PHOSPHONIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE

Chemical Property:

• Flash Point: 52?°C
• Density: 1.07?g/mL?at 20?°C(lit.)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 30
• Exact Mass: 763.42315797
• Heavy Atom Count: 48
• Complexity: 693

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trihexyl(tetradecyl)phosphonium bis(trifluoromethanesulfonyl)amide, min. 97% CYPHOS(R) IL 109 ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 10-22-34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC.C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F
• Uses: [P6,6,6,14][Ntf2] can be used in: The electrodeposition of nano and microcrystalline metals for electrochemical applications. The synthesis of amino acid ionic liquid functionalized graphene (AAIL-GR) applicable as a biosensor. The investigation of interactions between ionic liquids and fluorinated alkanes. The synthesis of pure rutile and anatase phases of nanocrystalline TiO2.

Technology Process of TRIHEXYL(TETRADECYL)PHOSPHONIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE

There total 2 articles about TRIHEXYL(TETRADECYL)PHOSPHONIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

(trihexyl)(tetradecyl)phosphonium bromide (654057-97-3) + bis(trifluoromethane)sulfonimide lithium (90076-65-6) → tetradecyl(trihexyl)phosphonium bistriflamide (460092-03-9)

Guidance literature:

In chloroform; water;

DOI:10.1016/j.tetlet.2012.02.003

Reference yield: 78.0%

trihexyl(tetradecyl)phosphonium chloride (258864-54-9) + bis(trifluoromethane)sulfonimide lithium (90076-65-6) → tetradecyl(trihexyl)phosphonium bistriflamide (460092-03-9)

Guidance literature:

In ethanol; at 20 ℃; for 16h;

DOI:10.1055/s-0033-1340846

upstream raw materials:

trihexyl(tetradecyl)phosphonium chloride

bis(trifluoromethane)sulfonimide lithium

(trihexyl)(tetradecyl)phosphonium bromide

Refernces

• 1、 Keith, Adam J.,Kosik, Stephen D.,Tillekeratne, L. M. Viranga,Mason, Mark R.. "Ion-tagged phosphines as ligands for suzuki coupling of aryl halides in a phosphonium ionic liquid". . p. 977 - 982. Retrieved 2014.
• 2、 Bradford, Brandy N.,Miller, Kevin M.. "Michael addition kinetics of ethyl acetoacetate and 2-ethylhexyl acrylate in ionic liquids". . p. 1855 - 1858. Retrieved 2012.
• 3、 Del Sesto, Rico E.,Corley, Cynthia,Robertson, Al,Wilkes, John S.. "Tetraalkylphosphonium-based ionic liquids". . p. 2536 - 2542. Retrieved 2005.
• 4、 Taylor, Sarah F. R.,Brittle, Stuart A.,Desai, Pratik,Jacquemin, Johan,Hardacre, Christopher,Zimmerman, William A.. "Factors affecting bubble size in ionic liquids". . p. 14306 - 14318. Retrieved 2017/07/22.