Zn₂((MeO(CH₂CH₂O)3C₆H₄)2(HCC)C₂₀H₈N₄C₄C₂₀H₈N₄(C₆H₄(OCH₂CH₂)3OMe)2(CCH))

Base Information

• Chemical Name: Zn₂((MeO(CH₂CH₂O)3C₆H₄)2(HCC)C₂₀H₈N₄C₄C₂₀H₈N₄(C₆H₄(OCH₂CH₂)3OMe)2(CCH))
• CAS No.: 1144514-33-9
• Molecular Formula: C₁₀₀H₉₄N₈O₁₆Zn₂
• Molecular Weight: 1794.67
• Mol file: 1144514-33-9.mol

Synonyms:

Chemical Property of Zn₂((MeO(CH₂CH₂O)3C₆H₄)2(HCC)C₂₀H₈N₄C₄C₂₀H₈N₄(C₆H₄(OCH₂CH₂)3OMe)2(CCH))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Zn₂((MeO(CH₂CH₂O)3C₆H₄)2(HCC)C₂₀H₈N₄C₄C₂₀H₈N₄(C₆H₄(OCH₂CH₂)3OMe)2(CCH))

There total 1 articles about Zn₂((MeO(CH₂CH₂O)3C₆H₄)2(HCC)C₂₀H₈N₄C₄C₂₀H₈N₄(C₆H₄(OCH₂CH₂)3OMe)2(CCH)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Zn2((MeO(CH2CH2O)3C6H4)2(THSCC)C20H8N4C4C20H8N4(C6H4(OCH2CH2)3OMe)2(CCTHS)) (1144514-32-8) → Zn2((MeO(CH2CH2O)3C6H4)2(HCC)C20H8N4C4C20H8N4(C6H4(OCH2CH2)3OMe)2(CCH)) (1144514-33-9)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane; (Ar); addn. of THF soln. of fluoride salt to CH2Cl2 soln. of porphyrin deriv., stirring at room temp. for 40 min; addn. of anhyd. CaCl2, stirring for 10 min, filtration, evapn., drying for 1 h;

DOI:10.1039/b814789b

Reference yield:

4-iodopyridine (15854-87-2) + Zn2((MeO(CH2CH2O)3C6H4)2(HCC)C20H8N4C4C20H8N4(C6H4(OCH2CH2)3OMe)2(CCH)) (1144514-33-9) → Zn2((MeO(CH2CH2O)3C6H4)2(NC5H4CC)C20H8N4C4C20H8N4(C6H4(OCH2CH2)3OMe)2(CCC5H4N)) (1051971-75-5)

Guidance literature:

With copper(l) iodide; triphenylphosphine; In triethylamine; N,N-dimethyl-formamide; (Ar); addn. of DMF and triethylamine to mixt. of porphyrin deriv., iodopyridine, palladium compd., phosphine deriv. and CuI, degassing, stirringat 40°C overnight; chromy. (silica, CH2Cl2/pyridine 0.5%/methanol 1%), chromy. (silica, CH2Cl2/pyridine/methanol from 99:0.5:0.5 to 98.5:0.5:1), reppn. by layeringCH2Cl2 soln. with pentane, NMR and MALDI;

DOI:10.1039/b814789b

upstream raw materials:

Zn₂((MeO(CH₂CH₂O)3C₆H₄)2(THSCC)C₂₀H₈N₄C₄C₂₀H₈N₄(C₆H₄(OCH₂CH₂)3OMe)2(CCTHS))

Downstream raw materials:

Zn₂((MeO(CH₂CH₂O)3C₆H₄)2(NC₅H₄CC)C₂₀H₈N₄C₄C₂₀H₈N₄(C₆H₄(OCH₂CH₂)3OMe)2(CCC₅H₄N))

Refernces