[(C₆H₅SCH₂CH₂SC₆H₅)2ClRu(C₁₀H₈N₂C₂H₂)RuCl(C₁₀H₈N₂)2]⁽²⁺⁾*2PF₆^(1-)

Base Information

• Chemical Name: [(C₆H₅SCH₂CH₂SC₆H₅)2ClRu(C₁₀H₈N₂C₂H₂)RuCl(C₁₀H₈N₂)2]⁽²⁺⁾*2PF₆^(1-)
• CAS No.: 94132-58-8
• Molecular Formula: C₆₀H₅₄Cl₂N₆Ru₂S₄*2F₆P
• Molecular Weight: 1550.37
• Mol file: 94132-58-8.mol

Synonyms:

Chemical Property of [(C₆H₅SCH₂CH₂SC₆H₅)2ClRu(C₁₀H₈N₂C₂H₂)RuCl(C₁₀H₈N₂)2]⁽²⁺⁾*2PF₆^(1-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(C₆H₅SCH₂CH₂SC₆H₅)2ClRu(C₁₀H₈N₂C₂H₂)RuCl(C₁₀H₈N₂)2]⁽²⁺⁾*2PF₆^(1-)

There total 2 articles about [(C₆H₅SCH₂CH₂SC₆H₅)2ClRu(C₁₀H₈N₂C₂H₂)RuCl(C₁₀H₈N₂)2]⁽²⁺⁾*2PF₆^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ammonium hexafluorophosphate + cis-dichlorobis(2,2′-bipyridine)ruthenium(II) (345911-20-8,19542-80-4,158060-65-2,34795-02-3,15746-57-3) + [(C6H5SCH2CH2SC6H5)2ClRu(C5H4NCHCHC5H4N)](1+)*PF6(1-)=[(C6H5SCH2CH2SC6H5)2ClRu(C5H4NCHCHC5H4N)]PF6 (94070-21-0) → [(C6H5SCH2CH2SC6H5)2ClRu(C10H8N2C2H2)RuCl(C10H8N2)2](2+)*2PF6(1-) (94132-58-8)

Guidance literature:

In ethanol; water; a mixt. of complex in 80% EtOH-20% H2O mixt. was heated for 6 h, NH4PF6was added; EtOH was evapd., solid was dissolved in acetone and filtered into ether, residue was chromd.;

Reference yield:

cis-dichlorobis(2,2′-bipyridine)ruthenium(II) (345911-20-8,19542-80-4,158060-65-2,34795-02-3,15746-57-3) + silver(I) hexafluorophosphate (26042-63-7) + [(C6H5SCH2CH2SC6H5)2ClRu(C5H4NCHCHC5H4N)](1+)*PF6(1-)=[(C6H5SCH2CH2SC6H5)2ClRu(C5H4NCHCHC5H4N)]PF6 (94070-21-0) → [(C6H5SCH2CH2SC6H5)2ClRu(C10H8N2C2H2)RuCl(C10H8N2)2](2+)*2PF6(1-) (94132-58-8)

Guidance literature:

In acetone; ((bpy)2RuCl2) was stirred at room temp. for 1 h in the presence of AgPF6, a soln. of complex was added and mixt. was refluxed for at least 8 h; volume was reduced, soln. was filtered into ether, residue was chromd.;

Reference yield:

ammonium cerium (IV) nitrate (16774-21-3) + [(C6H5SCH2CH2SC6H5)2ClRu(C10H8N2C2H2)RuCl(C10H8N2)2](2+)*2PF6(1-) (94132-58-8) → [(C6H5SCH2CH2SC6H5)2ClRu(C10H8N2C2H2)RuCl(C10H8N2)2](3+)*3PF6(1-) (94070-13-0)

Guidance literature:

With HPF₆; In acetonitrile; complex was dissolved in acetonitrile contg. a 5% molar excess of (NH4)2Ce(NO3)6 and 2 drops of concd. HPF6; after 5 min soln. was filtered into ether and ppt. was filtered off;;

upstream raw materials:

cis-dichlorobis(2,2′-bipyridine)ruthenium(II)

[(C₆H₅SCH₂CH₂SC₆H₅)2ClRu(C₅H₄NCHCHC₅H₄N)]⁽¹⁺⁾*PF₆^(1-)=[(C₆H₅SCH₂CH₂SC₆H₅)2ClRu(C₅H₄NCHCHC₅H₄N)]PF₆

silver(I) hexafluorophosphate

Downstream raw materials:

[(C₆H₅SCH₂CH₂SC₆H₅)2ClRu(C₁₀H₈N₂C₂H₂)RuCl(C₁₀H₈N₂)2]⁽³⁺⁾*3PF₆^(1-)

Refernces