Technology Process of ruthenium(II)(dichloroglyoxime)3(BC6H5)2
There total 2 articles about ruthenium(II)(dichloroglyoxime)3(BC6H5)2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
Pb;
In
nitromethane; chloroform;
Ru-contg. compd. (38 mmol), dichloroglyoxime (16 mmol), sponge lead (8.0mmol) were dissolved/suspended in CH3NO2 with stirring under Ar; heatin g to boiling, and a soln. of B-contg. compd. (11.5 mmol) in CHCl3 was added dropwise; refluxing for 2 h; addn. of addnl. amt. of H2Cl2Gm (8.0 mmol); refluxing for 3 h; the mixt.was dild. with a 2-fold vol. of MeOH; the ppt. was washed with H2O, aq. HCl, MeOH, Et2O, chloroform; elem. anal.;
DOI:10.1039/b107172f
- Guidance literature:
-
In
trifluoroacetic acid;
Ru-contg. compd. (6.2 mmol), B-contg. compd. (13 mmol), and a ligand (19mmol) were dissolved/suspended in TFA; the react. mixt. was refluxed fo r 10 h, left overnight, and dild. with MeOH; the ppt. was washed with water, aq. HCl, MeOH, Et2O, and a small amt. ofchloroform; the complex was extd. with benzene or chloroform and pptd. with hexane; the solid was washed with hexane and dried in vac.; elem. a nal.;
DOI:10.1039/b107172f
- Guidance literature:
-
In
N,N-dimethyl-formamide;
to a stirring soln./suspn. of Ru-contg. compd. in DMF was added dropwisea soln. of a 2-fold excess of n-butylamine in DMF for 2 h at -5° C; the mixt. was left overnight at room temp.; stirring at room temp. for 10 h; pptn. with a 2-fold vol. of H2O; solid was filtered, dried in vac., and dissolved in CHCl3; soln. was filtered through a Silasorb SPH-300 layer,dild. with hexane, and evapd. to dryness; the solid was washed with hex ane and dried in vac.; elem. anal.;
DOI:10.1039/b107172f
![2(CH<sub>3</sub>)4N<sup>(1+)</sup>*[Ru(OH)Cl<sub>5</sub>]<sup>(2-)</sup>=[(CH<sub>3</sub>)4N]2[Ru(OH)Cl<sub>5</sub>]](/Databaselist/images/loading.webp)
