1-Amino-3-(2-trimethylsilylethoxycarbonyl)pyridinium-mesitylensulfonat

Base Information

• Chemical Name: 1-Amino-3-(2-trimethylsilylethoxycarbonyl)pyridinium-mesitylensulfonat
• CAS No.: 87951-26-6
• Molecular Formula: C₉H₁₁O₃S*C₁₁H₁₉N₂O₂Si
• Molecular Weight: 438.62
• Mol file: 87951-26-6.mol

Synonyms:

Chemical Property of 1-Amino-3-(2-trimethylsilylethoxycarbonyl)pyridinium-mesitylensulfonat

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-Amino-3-(2-trimethylsilylethoxycarbonyl)pyridinium-mesitylensulfonat

There total 3 articles about 1-Amino-3-(2-trimethylsilylethoxycarbonyl)pyridinium-mesitylensulfonat which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

mesitylenesulfonylhydroxylamine (36016-40-7) + 3-Pyridincarbonsaeure-(2-trimethylsilylethylester) (87951-24-4) → 1-Amino-3-(2-trimethylsilylethoxycarbonyl)pyridinium-mesitylensulfonat (87951-26-6)

Guidance literature:

In dichloromethane; for 1h; Ambient temperature;

Reference yield:

nicotinic acid (59-67-6) → 1-Amino-3-(2-trimethylsilylethoxycarbonyl)pyridinium-mesitylensulfonat (87951-26-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 32.0 g / SOCl₂ / 1.5 h / Heating

2: 74 percent / Et₃N / benzene / 1 h / Heating

3: 71 percent / CH₂Cl₂ / 1 h / Ambient temperature

With thionyl chloride; triethylamine; In dichloromethane; benzene;

Reference yield:

nicotinic acid hydrochloride (636-79-3) → 1-Amino-3-(2-trimethylsilylethoxycarbonyl)pyridinium-mesitylensulfonat (87951-26-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 74 percent / Et₃N / benzene / 1 h / Heating

2: 71 percent / CH₂Cl₂ / 1 h / Ambient temperature

With triethylamine; In dichloromethane; benzene;

upstream raw materials:

mesitylenesulfonylhydroxylamine

3-Pyridincarbonsaeure-(2-trimethylsilylethylester)

nicotinic acid

nicotinic acid hydrochloride

Refernces