S-Ethyl-S-phenyl sulfoximine

Base Information

• Chemical Name: S-Ethyl-S-phenyl sulfoximine
• CAS No.: 1889-63-0
• Molecular Formula: C₈H₁₁NOS
• Molecular Weight: 169.247
• Hs Code.: 29350090
• European Community (EC) Number: 960-326-2
• Nikkaji Number: J3.102.502H
• Mol file: 1889-63-0.mol

Synonyms:S-Ethyl-S-phenyl sulfoximine;1889-63-0;ethyl-imino-oxo-phenyl-lambda6-sulfane;S-Ethyl-S-phenylsulfoximine;SCHEMBL3635347;ethyl(imino)phenyl-|E?-sulfanone;ethyl(imino)(phenyl)-l6-sulfanone;BAA88963;ethyl(imino)phenyl-lambda6-sulfanone;ethyl(imino)phenyl-$l^{6}-sulfanone;AKOS006311403;ETHYL(IMINO)PHENYL-??-SULFANONE;AS-59635;CS-0199348;EN300-315088;F76228

Chemical Property of S-Ethyl-S-phenyl sulfoximine

Chemical Property:

• XLogP3: 2.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 169.05613515
• Heavy Atom Count: 11
• Complexity: 212

Purity/Quality:

99% ^*data from raw suppliers

S-Ethyl-S-phenylsulfoximine 95% ^*data from reagent suppliers

Safty Information:

• Statements: 22
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCS(=N)(=O)C1=CC=CC=C1

Technology Process of S-Ethyl-S-phenyl sulfoximine

There total 33 articles about S-Ethyl-S-phenyl sulfoximine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

N-(2,2,2-trifluoroethyloxycarbonyl)ethyl phenyl sulfoximine → (phenyl)(ethyl)(imino)-λ6-sulfanone (121034-19-3,1889-63-0,121034-21-7)

Guidance literature:

With sulfuric acid; In water; at 110 ℃; for 2h;

DOI:10.1002/adsc.201300766

Reference yield: 91.0%

ethylphenylsulfoxide (51207-25-1,67529-33-3,104113-36-2,4170-80-3) → (phenyl)(ethyl)(imino)-λ6-sulfanone (121034-19-3,1889-63-0,121034-21-7)

Guidance literature:

With sodium azide; In neat (no solvent); at 50 ℃; for 0.5h;

DOI:10.1016/j.tetlet.2016.12.031

Reference yield: 90.0%

Ethyl phenyl sulfide (622-38-8) → (phenyl)(ethyl)(imino)-λ6-sulfanone (121034-19-3,1889-63-0,121034-21-7)

Guidance literature:

With diacetoxyiodo-3,4,5-trifluorobenzene; water; ammonium carbonate; at 25 ℃; for 16h; Green chemistry;

DOI:10.1002/cssc.201903430

upstream raw materials:

methyl-phenyl-thioether

racemic methyl phenyl sulfoxide

S-methyl-S-phenylsulfoximine

S-methyl-S-phenyl-N-(trimethylsilyl)sulfoximine

Downstream raw materials:

C₈H₁₁NOS

N-[3-(methyl)-benzoyl]-S-ethyl-S-phenylsulfoximine

Refernces

• 1、 Amri, Nasser,Wirth, Thomas. "Flow Electrosynthesis of Sulfoxides, Sulfones, and Sulfoximines without Supporting Electrolytes". . p. 15961 - 15972. Retrieved 2021/07/20.
• 2、 Chen, Hongyi,Chen, Li,He, Ze,Zeng, Qingle. "Blue light-promoted radical sulfoximido-chalcogenization of aliphatic and aromatic alkenes". supporting information. p. 2624 - 2627. Retrieved 2021/04/21.