dichloro-bis(diphenyl(2-thienyl)phosphine)platinum(II)

Base Information

• Chemical Name: dichloro-bis(diphenyl(2-thienyl)phosphine)platinum(II)
• CAS No.: 81380-87-2
• Molecular Formula: C₃₂H₂₆Cl₂P₂PtS₂
• Molecular Weight: 802.624
• Mol file: 81380-87-2.mol

Synonyms:

Chemical Property of dichloro-bis(diphenyl(2-thienyl)phosphine)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of dichloro-bis(diphenyl(2-thienyl)phosphine)platinum(II)

There total 4 articles about dichloro-bis(diphenyl(2-thienyl)phosphine)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

potassium tetrachloroplatinate(II) (10025-99-7) + diphenyl(2-thienyl)phosphine (61157-16-2) → dichloro-bis(diphenyl(2-thienyl)phosphine)platinum(II) (81380-87-2)

Guidance literature:

In dichloromethane; water; stirring of ligand soln. in CH2Cl2 with an aq. soln. of K2PtCl4; sepn. of layers, drying of organic layer over MgSO4, filtration, removalof solvent, addn. of CH2Cl2, precipitation with hexanes, filtration, el em. anal.;

DOI:10.1139/V07-033

Reference yield:

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + {cis-molybdenum(0)pentacarbonyl(diphenyl-2-thienylphosphine)2} → {molybdenum(0)pentacarbonyldiphenyl-2-thienylphosphine} (117753-33-0) + dichloro-bis(diphenyl(2-thienyl)phosphine)platinum(II) (81380-87-2) + trans-Mo(CO)4(Ph2P(2-C4H3S))2

Guidance literature:

In tetrahydrofuran; refluxing for 2 h under an inert atmosphere;; products identified by 31P NMR- and IR-spectroscopy;;

DOI:10.1016/S0020-1693(00)87504-0

Reference yield:

bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + diphenyl(2-thienyl)phosphine (61157-16-2) → dichloro-bis(diphenyl(2-thienyl)phosphine)platinum(II) (81380-87-2)

Guidance literature:

In dichloromethane; to CH2Cl2 soln. of Pt-complex soln. of ligand in CH2Cl2 was added dropwise under N2, stirred at room temp. for 30 min; solvent was removed in vacuo, washed with hexane, recrystd. from CH2Cl2;

upstream raw materials:

bis(benzonitrile)dichloroplatinum(II)

diphenyl(2-thienyl)phosphine

dichloro(1,5-cyclooctadiene)platinum(ll)

potassium tetrachloroplatinate(II)

Refernces

• 1、 Jain,Clark,Jain. "Tertiary phosphines containing 2-thienyl group and their coordination chemistry". . p. 135 - 143. Retrieved 2007/10/03.