ReMo(C₅H₅)H(P(C₆H₅)2)(CO)6

Base Information

• Chemical Name: ReMo(C₅H₅)H(P(C₆H₅)2)(CO)6
• CAS No.: 134594-79-9
• Molecular Formula: C₂₃H₁₆MoO₆PRe
• Molecular Weight: 701.497
• Mol file: 134594-79-9.mol

Synonyms:

Chemical Property of ReMo(C₅H₅)H(P(C₆H₅)2)(CO)6

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ReMo(C₅H₅)H(P(C₆H₅)2)(CO)6

There total 1 articles about ReMo(C₅H₅)H(P(C₆H₅)2)(CO)6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

decacarbonyldirhenium(0) (14285-68-8) + cyclopentadienylmolybdenum tricarbonyl dimer + diphenylphosphane (829-85-6) → [Re2(μ-H)(μ-PPh2)(CO)8] + octacarbonyl-bis(μ-diphenylphosphido)-dirhenium + Mo2(C5H5)2(P(C6H5)2)2(CO)4 (102777-57-1) + Re(CO)4(H)(P(C6H5)2)Mo(C5H5)(CO)2 (134594-79-9)

Guidance literature:

In xylene; (Ar), 10 h at 180°C; dissolved in CH2Cl2, chromatographed (column, CH2Cl2/n-hexane), 12 h oxidation by air, filtered, crystallized from CH2Cl2/n-hexane, elem. anal., (31)P-NMR, IR;

Reference yield: 86.0%

Re(CO)4(H)(P(C6H5)2)Mo(C5H5)(CO)2 (134594-79-9) + tetraethylammonium chloride (56-34-8) + 1,8-diazabicyclo[5.4.0]undec-7-ene (6674-22-2,83329-50-4) → (C2H5)4N(1+)*Re(CO)4(P(C6H5)2)Mo(C5H5)(CO)2(1-) = {(C2H5)4N}{Re(CO)4(P(C6H5)2)Mo(C5H5)(CO)2} (134594-84-6)

Guidance literature:

In tetrahydrofuran; methanol; (Ar), reacted with DBU for 3 h in THF; precipitated with Et4NCl from methanolic solution, elem. anal.;

Reference yield: 78.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + Re(CO)4(H)(P(C6H5)2)Mo(C5H5)(CO)2 (134594-79-9) + 1,8-diazabicyclo[5.4.0]undec-7-ene (6674-22-2,83329-50-4) → Re(CO)4(P(C6H5)2)(AuP(C6H5)3)Mo(C5H5)(CO)2 (134594-80-2) + 1,8-diazabicyclo<5.4.0>undec-7-ene hidrochloride (78204-84-9)

Guidance literature:

In tetrahydrofuran; (Ar), reacted for 4 h with DBU, Au-compound added; filtered after 30 min, reduced to dryness, HPLC (CH2Cl2/n-hexane, 23.3 min), elem. anal.;

upstream raw materials:

decacarbonyldirhenium⁽⁰⁾

diphenylphosphane

Downstream raw materials:

(C₂H₅)4N⁽¹⁺⁾*Re(CO)4(P(C₆H₅)2)Mo(C₅H₅)(CO)2^(1-) = {(C₂H₅)4N}{Re(CO)4(P(C₆H₅)2)Mo(C₅H₅)(CO)2}

Re(CO)4(P(C₆H₅)2)(AuP(C₆H₅)3)Mo(C₅H₅)(CO)2

1,8-diazabicyclo<5.4.0>undec-7-ene hidrochloride

ReMo(C₅H₅)I(P(C₆H₅)2)(CO)6