C₆H₅(C₆H₄NC₆H₃)C₅H₃NCH₃

Base Information

• Chemical Name: C₆H₅(C₆H₄NC₆H₃)C₅H₃NCH₃
• CAS No.: 1187662-57-2
• Molecular Formula: C₂₄H₁₈N₂
• Molecular Weight: 334.42
• Mol file: 1187662-57-2.mol

Synonyms:

Chemical Property of C₆H₅(C₆H₄NC₆H₃)C₅H₃NCH₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆H₅(C₆H₄NC₆H₃)C₅H₃NCH₃

There total 1 articles about C₆H₅(C₆H₄NC₆H₃)C₅H₃NCH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-phenyl-9H-carbazol-3-boronic acid (854952-58-2) + 2-chloro-4-picoline (3678-62-4) → C6H5(C6H4NC6H3)C5H3NCH3 (1187662-57-2)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In toluene; at 110 ℃; for 48h;

DOI:10.1016/j.jorganchem.2009.03.002

Reference yield: 29.0%

potassium tetrachloroplatinate(II) (10025-99-7) + C6H5(C6H4NC6H3)C5H3NCH3 (1187662-57-2) + acetylacetone (123-54-6,81235-32-7) → Pt(C6H5(C6H3NC6H3)C5H3NCH3)(CH3COCHCOCH3) (1240116-88-4)

Guidance literature:

With Na₂CO₃; In 2-ethoxy-ethanol; water; (N2); ligand and K2PtCl4 in 2-ethoxyethanol/H2O (3:1, v/v) were heated at 80°C for 16 h, added to H2O at room temp., solid was washed with water, dried in vac., at 50°C, treated with acac, Na2CO3 in 2-ethoxyethanol at 100°C for 16 h; evapd., column chromy. (silica gel, CH2Cl2/hexane), elem. anal.;

DOI:10.1016/j.jorganchem.2009.03.002

upstream raw materials:

N-phenyl-9H-carbazol-3-boronic acid

2-chloro-4-picoline

Downstream raw materials:

Pt(C₆H₅(C₆H₃NC₆H₃)C₅H₃NCH₃)(CH₃COCHCOCH₃)

Refernces