O-(3.5-dinitro-benzoyl)-campestanol

Base Information

• Chemical Name: O-(3.5-dinitro-benzoyl)-campestanol
• CAS No.: 116282-74-7
• Molecular Formula: C₃₅H₅₂N₂O₆
• Molecular Weight: 596.808
• Mol file: 116282-74-7.mol

Synonyms:

Chemical Property of O-(3.5-dinitro-benzoyl)-campestanol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of O-(3.5-dinitro-benzoyl)-campestanol

There total 8 articles about O-(3.5-dinitro-benzoyl)-campestanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

campestanol (474-60-2) + 3,5-dinitrobenoyl chloride (99-33-2) → O-(3.5-dinitro-benzoyl)-campestanol (116282-74-7,116403-33-9,120663-52-7)

Guidance literature:

With pyridine;

DOI:10.1021/ja01849a080 DOI:10.1021/ja01620a050

Reference yield:

campesteryl acetate (1900-53-4) → O-(3.5-dinitro-benzoyl)-campestanol (116282-74-7,116403-33-9,120663-52-7)

Guidance literature:

Multi-step reaction with 2 steps

1: platinum; glacial acetic acid / 20 °C / Hydrogenation_.Hydrolyse des erhaltenen O-Acetyl-Derivats

2: pyridine

With pyridine; acetic acid; platinum;

DOI:10.1021/ja01849a080

Reference yield:

(10S)-3t-Hydroxy-10r.13t-dimethyl-17t-((1R:4R)-1.4.5-trimethyl-hexen-(2t)-yl)-(9cH.14cH)-Δ5.7-dodecahydro-1H-cyclopenta[a]phenanthren (128-27-8) → 3.5-dinitro-benzoic acid-(5α.10α-ergostanyl-(3α)-ester) (116282-74-7,116403-33-9,120663-52-7)

Guidance literature:

Multi-step reaction with 5 steps

1: sodium; ethanol

2: ethanol / 190 °C / Isolierung aus Gemischen mit 5α.10α-Ergostadien-(7.22t)-ol-(3β) durch Faellung als Verbindung mit Digitonin

4: platinum; glacial acetic acid / 60 °C / Hydrogenation_.Hydrolyse des gebildeten, nicht rein erhaltenen O-Acetyl-Derivats

5: pyridine

With pyridine; ethanol; sodium; acetic acid; platinum;

DOI:10.1080/10473289.2002.10470843

upstream raw materials:

5α,10α-ergostanol-(3β)

(10S)-3t-Hydroxy-10r.13t-dimethyl-17t-((1R:4R)-1.4.5-trimethyl-hexen-(2t)-yl)-(9cH.14cH)-Δ^5.7-dodecahydro-1H-cyclopenta[a]phenanthren

5α.10α-ergostadien-(7.22t)-ol-(3α)

5α.10α-ergostadien-(7.22t)-ol-(3β)