gallium(III) iodide, triphenylphosphine adduct

Base Information

• Chemical Name: gallium(III) iodide, triphenylphosphine adduct
• CAS No.: 17764-59-9
• Molecular Formula: C₁₈H₁₅GaI₃P
• Molecular Weight: 712.727
• Mol file: 17764-59-9.mol

Synonyms:

Chemical Property of gallium(III) iodide, triphenylphosphine adduct

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of gallium(III) iodide, triphenylphosphine adduct

There total 3 articles about gallium(III) iodide, triphenylphosphine adduct which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

gallium(III) iodide (13450-91-4) + triphenylphosphine (603-35-0) → gallium(III) iodide, triphenylphosphine adduct (17764-59-9)

Guidance literature:

In diethyl ether; under N2, 1 equiv. of phosphine in Et2O was added to Et2O soln. of Ga-compd., stirring at room temp. for 15 h; ppt. was filtered off, washed with Et2O, dried in vac., elem. anal.;

DOI:10.1016/j.poly.2007.05.008

Reference yield:

gallium (7440-55-3) + iodine (7553-56-2,12190-71-5,8031-47-8) → GaI3*PPh3 (17764-59-9)

Guidance literature:

With triphenylphosphine; In toluene; Sonication; mixt. of Ga metal and di-iodine in toluene warmed (N2, Ga melted), pale green powder ("GaI"); treatment with toluene soln. of PPh3;

DOI:10.1016/S0277-5387(00)86809-6

Reference yield:

gallium(III) iodide + triphenylphosphine (603-35-0) → gallium(III) iodide, triphenylphosphine adduct (17764-59-9)

Guidance literature:

In toluene; Glovebox; Inert atmosphere;

DOI:10.1002/chem.201202954

upstream raw materials:

gallium

iodine

gallium(III) iodide

triphenylphosphine

Downstream raw materials:

GaClI₂(P(C₆H₅)3)

GaBrI₂(P(C₆H₅)3)

Refernces

• 1、 Chen, Fu,Ma, Guibin,Bernard, Guy M.,Wasylishen, Roderick E.,Cavell, Ronald G.,McDonald, Robert,Ferguson, Michael J.. "An investigation of 1:1 adducts of gallium trihalides with triarylphosphines by solid-state 69/71Ga and 31P NMR spectroscopy". supporting information. p. 2826 - 2838. Retrieved 2013/03/14.
• 2、 Brown, Martyn A.,Castro, Jesus A.,Tuck, Dennis G.. "Spectroscopic and crystallographic studies of phosphino adducts of gallium(III) iodide". . p. 333 - 341. Retrieved 2007/10/03.