{C₅H₄CH₃(CO)2Mn}2SC₆H₂(CH₃)3⁽¹⁺⁾*PF₆^(1-) = {C₅H₄CH₃(CO)2Mn}2SC₆H₂(CH₃)3PF₆

Base Information

• Chemical Name: {C₅H₄CH₃(CO)2Mn}2SC₆H₂(CH₃)3⁽¹⁺⁾*PF₆^(1-) = {C₅H₄CH₃(CO)2Mn}2SC₆H₂(CH₃)3PF₆
• CAS No.: 136379-13-0
• Molecular Formula: C₂₅H₂₅Mn₂O₄S*F₆P
• Molecular Weight: 676.377
• Mol file: 136379-13-0.mol

Synonyms:

Chemical Property of {C₅H₄CH₃(CO)2Mn}2SC₆H₂(CH₃)3⁽¹⁺⁾*PF₆^(1-) = {C₅H₄CH₃(CO)2Mn}2SC₆H₂(CH₃)3PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {C₅H₄CH₃(CO)2Mn}2SC₆H₂(CH₃)3⁽¹⁺⁾*PF₆^(1-) = {C₅H₄CH₃(CO)2Mn}2SC₆H₂(CH₃)3PF₆

There total 1 articles about {C₅H₄CH₃(CO)2Mn}2SC₆H₂(CH₃)3⁽¹⁺⁾*PF₆^(1-) = {C₅H₄CH₃(CO)2Mn}2SC₆H₂(CH₃)3PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

silver(I) hexafluorophosphate (26042-63-7) + C5H4CH3(CO)2MnSC6H2(CH3)3 (136378-99-9) → methylcyclopentadienyl manganese(I) tricarbonyl + {C5H4CH3(CO)2Mn}2SC6H2(CH3)3(1+)*PF6(1-) = {C5H4CH3(CO)2Mn}2SC6H2(CH3)3PF6 (136379-13-0)

Guidance literature:

In toluene; carried out with exclusion of air and moisture; 1 equiv of AgPF6 added to a stirred soln. of the Pd complex; mixt. stirred for further 20 min. at room temp.; volume reduced in vac., pentane added, filtered through silanized silica gel, elution with CH2Cl2, crystn. from CH2Cl2-Et2O (1:1) at -30°C; elem. anal.;

upstream raw materials:

silver(I) hexafluorophosphate

C₅H₄CH₃(CO)2MnSC₆H₂(CH₃)3

Refernces