Trihexylboron

Base Information

• Chemical Name: Trihexylboron
• CAS No.: 1188-92-7
• Molecular Formula: C18H39B
• Molecular Weight: 266.319
• Hs Code.: 2931900090
• Mol file: 1188-92-7.mol

Synonyms:trihexyl-borane;Borane,trihexyl;Trihexyl-boran;

Chemical Property of Trihexylboron

Chemical Property:

• Vapor Pressure: 0.000184mmHg at 25°C
• Boiling Point: 339.2oC at 760 mmHg
• Flash Point: 158.9oC
• PSA: 0.00000
• Density: 0.766g/cm3
• LogP: 7.22210

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Trihexylboron

There total 5 articles about Trihexylboron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

(C2H5)2O*(chloro)dihydroborane + cyclohexene (110-83-8) → Trihexylboran; Tri-n-hexylbor (1188-92-7) + dicyclohexylboron chloride (36140-19-9)

Guidance literature:

Reference yield:

1-hexene (592-41-6,25067-06-5) + tripentylborane (1883-38-1) → 1-penten (109-67-1) + Trihexylboran; Tri-n-hexylbor (1188-92-7)

Guidance literature:

DOI:10.1021/ja01533a025

Reference yield:

triethylamine-borane (1722-26-5) + 2-hexene (592-43-8) → Trihexylboran; Tri-n-hexylbor (1188-92-7) + triethylamine (121-44-8)

Guidance literature:

In neat (no solvent); heating to 200°C in an autoclave;;

DOI:10.1021/ja01527a010

upstream raw materials:

1-hexene

tripentylborane

triethylamine-borane

2-hexene

Downstream raw materials:

tetradec-7-ene

decan-4-one

dec-1-en-3-yne

Heptanophenone

Refernces

• 1、 Cole, Thomas E.,Bakshi, Raman K.,Srebnik, Morris,Singaram, Bakthan,Brown, Herbert C.. "Organoboranes. 49. An examination of convenient procedures for the generation of borane and monoalkyl- and dialkylboranes from lithium borohydride and monoalkyl- and dialkylborohydrides". . p. 2303 - 2307. Retrieved 2008/10/08.