7-Tetradecene

Base Information

• Chemical Name: 7-Tetradecene
• CAS No.: 10374-74-0
• Molecular Formula: C14H28
• Molecular Weight: 196.376
• Hs Code.: 2901299090
• European Community (EC) Number: 233-815-7
• UNII: 3V3074NJ3L
• DSSTox Substance ID: DTXSID001020809
• Nikkaji Number: J133.002K,J208.983A
• Wikidata: Q27160506
• Mol file: 10374-74-0.mol

Synonyms:7-tetradecene;E-7-tetradecene

Chemical Property of 7-Tetradecene

Chemical Property:

• Vapor Pressure: 0.0322mmHg at 25°C
• Refractive Index: n20/D 1.438
• Boiling Point: 250oC(lit.)
• Flash Point: 211 °F
• PSA: 0.00000
• Density: 0.764 g/mL at 25oC(lit.)
• LogP: 5.48340
• XLogP3: 6.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 10
• Exact Mass: 196.219100893
• Heavy Atom Count: 14
• Complexity: 99.2

Purity/Quality:

98%,99%, ^*data from raw suppliers

7-Tetradecene >97.0%(GC) ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Aliphatics, Unsaturated
• Canonical SMILES: CCCCCCC=CCCCCCC
• Isomeric SMILES: CCCCCC/C=C/CCCCCC

Technology Process of 7-Tetradecene

There total 90 articles about 7-Tetradecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

oct-1-ene (111-66-0,25068-25-1) → tetradec-7-ene (10374-74-0)

Guidance literature:

With silica immobilized second generation Hoveyda-Grubbs catalyst; In hexane; at 19.84 ℃; for 4h;

DOI:10.1002/adsc.200800211

Reference yield: 67.0%

oct-1-ene (111-66-0,25068-25-1) → 3‐decene (19398-37-9) + 4-octene (592-99-4,7642-15-1,14850-23-8) + oct-3-ene (14850-22-7,14919-01-8,138663-42-0,592-98-3) + 2-octene (111-67-1) + (E,Z)-tridec-6-ene (24949-38-0) + dodecene-5 (42714-70-5) + 4-undecene (20810-21-3) + tetradec-7-ene (10374-74-0) + cis,trans-2-nonylene (2216-38-8)

Guidance literature:

With rhenium(VII) oxide on aluminum oxide; In supercritical CO₂; at 35 ℃; for 2h; under 67506.8 Torr; chemoselective reaction; Inert atmosphere; Autoclave;

DOI:10.1039/b815121k

Reference yield: 51.0%

oct-1-ene (111-66-0,25068-25-1) + crotonaldehyde (123-73-9,4170-30-3) → (E)-2-Nonenal (18829-56-6) + tetradec-7-ene (10374-74-0)

Guidance literature:

With Hoveyda-Grubbs catalyst second generation; In dichloromethane; at 20 ℃; for 8h; Schlenk technique; Inert atmosphere;

DOI:10.1016/j.apcata.2014.08.032

upstream raw materials:

n-octyne

Trihexylboran; Tri-n-hexylbor

8-(Phenylseleno)-7-tetradecanol

8-methylselanyl-tetradecan-7-ol

Downstream raw materials:

2,3-dihexyloxirane

oenanthic acid

tetradecane-7,8-dione

4-methoxy-1-tetradecylbenzene

Refernces

• 1、 Ookoshi, Tooru,Onaka, Makoto. "A remarkable Mo catalyst for olefin metathesis: Hexagonal mesoporous silica-supported molybdenum oxide (MoO3/HMS)". . p. 2399 - 2400. Retrieved 1998.
• 2、 Imbrich, Dominik A.,Elser, Iris,Frey, Wolfgang,Buchmeiser, Michael R.. "First Neutral and Cationic Tungsten Imido Alkylidene N-Heterocyclic Carbene Complexes". . p. 2996 - 3002. Retrieved 2017.
• 3、 Dobereiner, Graham E.,Erdogan, Gulin,Larsen, Casey R.,Grotjahn, Douglas B.,Schrock, Richard R.. "A one-pot tandem olefin isomerization/metathesis-coupling (ISOMET) reaction". . p. 3069 - 3076. Retrieved 2014.
• 4、 Gleeson, Ellen C.,Wang, Zhen J.,Jackson, W. Roy,Robinson, Andrea J.. "Divergent Approach to a Family of Tyrosine-Derived Ru-Alkylidene Olefin Metathesis Catalysts". . p. 7205 - 7211. Retrieved 2015.
• 5、 ?ztürk, Bengi ?zgün,Durmu?, Burcu,Karabulut ?ehito?lu, Solmaz. "Olefin metathesis in air using latent ruthenium catalysts: Imidazole substituted amphiphilic hydrogenated ROMP polymers providing nano-sized reaction spaces in water". . p. 5807 - 5815. Retrieved 2018.
• 6、 Yuan, Jian,Fracaroli, Alejandro M.,Klemperer, Walter G.. "Convergent Synthesis of a Metal-Organic Framework Supported Olefin Metathesis Catalyst". . p. 2149 - 2155. Retrieved 2016.
• 7、 Bakala, Paul Celestin,Briot, Emmanuel,Millot, Yannick,Piquemal, Jean-Yves,Bregeault, Jean-Marie. "Comparison of olefin metathesis by rhenium-containing γ-alumina or silica-aluminas and by some mesoporous analogues". . p. 61 - 70. Retrieved 2008.
• 8、 Onaka, Makoto,Oikawa, Takashi. "Olefin metathesis over mesoporous alumina-supported rhenium oxide catalyst". . p. 850 - 851. Retrieved 2002.
• 9、 Dinger, Maarten B.,Mol, Johannes C.. "High turnover numbers with ruthenium-based metathesis catalysts". . p. 671 - 677. Retrieved 2002.
• 10、 Renom-Carrasco, Marc,Gajewski, Piotr,Pignataro, Luca,De Vries, Johannes G.,Piarulli, Umberto,Gennari, Cesare,Lefort, Laurent. "Asymmetric Transfer Hydrogenation of Ketones with Modified Grubbs Metathesis Catalysts: On the Way to a Tandem Process". . p. 515 - 519. Retrieved 2016.